In the previous publicat ions [ 1 , 2 ] the theoret ical background of the topological effect on molecular orbital energies (TEMO) was worked out and illustrated with a number of ^-electronic carbocyclic and nitrogen heterocyclic molecules. The T E M O concept provides a general relation for the M O energy patterns of the S and T isomers. The S and T isomers are topologically related molecules ...

In this paper, the idea of ∈ , ∨ q ˘ -bipolar fuzzy id="M4"> b -ideals and an id="M5"> ideals id="M6"> BCK / BCI -algebras is delivered, their related p...

Morpholino oligonucleotides (MO) can induce gene silencing by binding to a target mRNA and inhibiting its translation, and this technique has been especially successful in studies of embryonic development in various vertebrates. But in mice MO-induced downregulation of target genes has not been widely reported. In this study, we examined whether MO delivery using ethoxylated polyethylenimine (E...

There is a considerable interest in low activation and high heat resistant materials for fusion applications. Tungsten (W) would fulfill these requirements for plasma facing components of future fusion power plants. A novel method developed by SNL to enhance the thermal and dimensional stability of W requires depositing materials such as Re and Mo as a thin coating on the surface of dendritic W...

In this paper we explore the ethylation of dinitrogen (employing [Et3O][BAr4]; Arf = 3,5(CF3)2C6H3) in [HIPTN3N]Mo (Mo) complexes ([HIPTN3N] = [N(CH2CH2NHIPT)3]; HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) with the objective of developing a catalytic cycle for the conversion of dinitrogen into triethylamine. A number of possible intermediates in a hypothetical catalytic cycle have been isolated and char...

Take five: A unique quintuply bonded dimolybdenum complex [Mo(2)(μ-Li){μ-HC(N-2,6-Et(2)C(6)H(3))(2)}(3)] (see picture) was synthesized and characterized. The Mo-Mo interaction includes an unexpected bridging Li(+) ion. Calculations indicate the bridging Li(+) ion does not perturb the Mo-Mo bond length (2.0612(4) Å), but results in a relatively small effective Mo-Mo bond order of 3.67.

Let G be a simple connected graph with vertex set id="M2"> V = open="{" close="}" v 1 , 2 … n and id="M3"> d i the degree of id="M4"> . id="M5"> <m...

We introduce an additive s , t -functional inequality where id="M3"> and id="M4"> are nonzero complex numbers with id="M5"> 2 open="|" close="|"> + &lt; 1 . Using the direct method fixed ...

Relativistic calculations of the induced proton polarization in quasifree electron scattering on 12 C are presented. Good agreement with the experimental data of Woo et al. is obtained. The relativistic calculations yield a somewhat better description of the data than the non-relativistic ones. Differences between the two approaches are more pronounced at larger missing momenta suggesting furth...