Field quantitative estimation of reaction kinetics is required to enhance our understanding of biogeochemical reactions in aquifers. We extended the analytical solution developed by Haggerty et al. (1998) to model an entire 1st order reaction chain and estimate the kinetic parameters for each reaction step of the denitrification process. We then assessed the ability of this reaction chain to mo...

The immediate effects of tillage on protected soil C and N pools and on trace gas emissions from soils at precultivation levels of native C remain largely unknown. We measured the response to cultivation of CO2 and N2O emissions and associated environmental factors in a previously uncultivated U.S. Midwest Alfisol with C concentrations that were indistinguishable from those in adjacent late suc...

Nitrous oxide (N2O) is a potent greenhouse gas that is produced during microbial nitrogen transformation processes such as nitrification and denitrification. Soils represent the largest sources of N2O emissions with nitrogen fertilizer application being the main driver of rising atmospheric N2O concentrations. Soil biochar amendment has been proposed as a promising tool to mitigate N2O emission...

[1] An eddy covariance (EC) system with a tunable diode laser trace gas analyzer was used in a field setting in Ireland to measure N2O emissions on a continuous basis over an eight-month period, spanning a range of seasonal conditions. Intensely-grazed grassland fields within the footprint area of the EC sensors were subject to chemical fertilizer and slurry applications in order to boost grass...

Peatlands cover more than 30% of the Finnish land area and impact N2O fluxes. Denitrifiers release N2O as an intermediate or end product. In situ N2O emissions of a near pH neutral pristine fen soil in Finnish Lapland were marginal during gas chamber measurements. However, nitrate and ammonium fertilization significantly stimulated in situ N2O emissions. Stimulation with nitrate was stronger th...

[1] Although the oceans are a significant source of the greenhouse gas nitrous oxide (N2O) to the atmosphere, the magnitude and characteristics of this source are poorly constrained. We present here stable isotope and isotopomer (intramolecular distribution of N within the linear NNO molecule) results for N2O and oxygen stable isotopic data for dissolved O2 from Station ALOHA in the subtropical...

The land disposal of waste and wastewater is a major source of N2O emission. This is due to the presence of high concentrations of nitrogen (N) and carbon in the waste. Abattoir wastewater contains 186 mg/L of N and 30.4 mg/L of P. The equivalent of 3 kg of abattoir wastewater-irrigated soil was sieved and taken in a 4-L plastic container. Abattoir wastewater was used for irrigating the plants ...

dissolved organic nitrogen (don) is an important constituent of dissolved organic matter (dom). it has a considerable effect on total dissolved soil nitrogen and it is very important as a nitrogen source of many aquatic and terrestrial ecosystems. dissolved inorganic nitrogen, which is another form of total soil dissolved nitrogen, includes no3, no2 and nh4, which is very important for plant nu...

Nitrogen from fertilisers and crop residues can be lost as nitrous oxide (N2O), a greenhouse gas that causes an increase in global warming and also depletes stratospheric ozone. Nitrous oxide emissions, soil chemical status, temperature and N2O concentration in the soil atmosphere were measured in a ®eld experiment on soil compaction in loam and sandy loam (cambisols) soils in south-east Scotla...

Nitrogen availability directly affects the microalgal metabolism. A thermophilic cyanobacterium named Thermosynechococcus CL-1 was cultivated in a continuous system to evaluate the effects of NO3 fluxes on the biomass production, bioenergy production, and CO2 fixation. The results show that decreasing the NO3 flux to a N-deprived level (1.01 mM/d) enhances the carbohydrate content in TCL-1 to 4...