There is currently experimental interest in assemblies of Gd2O3 clusters. This has motivated the present study in which a single such cluster in free space is examined quantitatively by spin-density functional theory, with appropriate relativistic corrections incorporated for Gd. First, the nuclear geometry of the cluster is optimized, and it is found to be such that the two Gd atoms lie in a s...

2014 Fast electron energy loss spectroscopy (FEELS) is used to obtain the various optical constants over a large energy range in Sc, Sc2O3, Y, Y2O3, Gd, Gd2O3, Dy, LaF3, GdF3, DyF3, Th, ThF4, U and UF4. For the first time a comprehensive study of the 3p to 6p spectra is performed in the 30-60 eV range, Z varying between 21 and 92. Interesting common features of these resonant p spectra are emph...