H A method for detection of aromatic organics in groundwater has been tested. It was found that use of surface-enhanced Raman scattering and an octadecylthiol coating on roughened silver produced a system which could partition the organics out of water into the strongly Raman enhanced region near the silver surface. The selectivity of the method was illustrated with the three isomers of xylene....

Abstract We give short elementary expositions of combinatorial proofs some variants Euler's partition identity that were first addressed analytically by George Andrews, and later combinatorially others. The method using certain matrices to concisely explain these bijections, based on ideas used in a previous manuscript the author, enables us also new generalizations two results.

Diacylphosphatidylinositol (PI) is the starting reactant in the process of phosphatidylinositide-related signal transduction mediated through the lipid raft domain. We investigated intermolecular interactions of PI with major raft components, sphingomyelin (SM) and cholesterol (Chol), using surface pressure-molecular area (π-A) isotherm measurements. The classical mean molecular area versus com...

Monolayer films of a water-soluble surfactant, 4-octaneamido-2,2,6,6-tetramethyl-1-piperidinyloxy (C8-TEMPO) were investigated at the air/water interface. An electrochemical, horizontal touch method was developed to measure the equilibrium surface concentrations (gamma) of C8TEMPO. The dependence of gamma on the solution concentration followed a Langmuir isotherm and yielded the partition const...

On the basis of OCED Guideline 106, batch sorption studies were employed to reveal sorption of atrazine by amending biochar in tropical soils, namely, laterite, paddy soil and dry red soil. Biochar,a micro-porosity and great surface product, was generated by pyrolysis of manioc wastes at 750°C(BC750) and modified substances(MC750) were produced by loading Fe. The mechanism of sorption was exami...

Surface partitioning of 2,2,6,6-tetramethyl-1-piperidynyloxy radical (Tempo) to the air/water interface follows a Langmuir isotherm. The partition constant was obtained by the surface tension measurements in the concentration range of 1.0 x 10(-4)-2.4 x 10(-3) M yielding K = 640 +/- 99 M(-1). The lateral mobility of Tempo at the air/water interface was measured electrochemically in the surface ...

Analytical ultracentrifugation is one of the classical techniques for the study of protein interactions and protein self-association. Recent instrumental and computational developments have significantly enhanced this methodology. In this paper, new tools for the analysis of protein self-association by sedimentation velocity are developed, their statistical properties are examined, and consider...

The thermodynamic and transport properties of diffusing species in microporous materials are strongly influenced by their interactions with the confining framework, which provide the energy landscape for the transport process. The simple topology and the cellular nature of the alpha cages of a ZK4 zeolite suggest that it is appropriate to apply to the study of the problem of diffusion in tight ...