Abstract As a monomer, the [N-(alanine)] para-styrene sulfonamide (ASS) was prepared, from the reaction of para-styrene sulfonyl chloride and (S)-(+)-alanine in the presence of KOH 1M as a base, and CH3Cl was used as solvent. The monomer confirmed using FT-IR and 1H-NMR spectroscopy. Polystyrene [N-(alanine) sulfonamide] (PASS) was also prepared from the polymerization of [N-(alanine)] pa...

Supported catalysts are important tools for developing green-economy-based processes. Palladium nanoparticles (NPs) that immobilized on two fibers developed as metal scavengers (i.e., Smopex®-234 and Smopex®-111, 1% w/w) have been prepared tested in copper-free cyclocarbonylative Sonogashira reactions. Their catalytic activity has compared with of a homogeneous catalyst PdCl2(PPh3)2). Pd/Smopex...

Treatment of 1-(n-butyl)-3-N-(2-Ar)acetamido-1, 3-imidazolium chloride (Ar=furylmethyl,phenylmethyl) with excess K2CO3 and [PdCl2(L−L)] (L−L=2 PPh3, dppf) afforded orange compounds composition [(1-(n-butyl)-3-N-(2-Ar)acetamido-1,3-imidazol-2-ylidene)]2Pd (Ar=furylmethyl; phenylmethyl). These complexes were characterized by NMR (1H 13C{1H} NMR), IR micro-analysis data. Subsequently, the catalyti...

applying a ni-p electroless coat on the surface of bn(h) particles has a beneficial effect on their wettability in vortex technique during composite manufacturing. in this investigation, different preliminary treatments consisting of different combinations of surface oxidation, sensitization and activation have been investigated. the results obtained from scanning electron microscope (sem) and ...