The mineralisation kinetics of petroleum refinery effluent (PRE) by Fenton oxidation were evaluated. Within the ambit of the experimental data generated, first-order kinetic model (FKM), generalised lumped kinetic model (GLKM), and generalized kinetic model (GKM) were tested. The obtained apparent kinetic rate constants for the initial oxidation step (k'2), their final oxidation step (k'1), and...

There have occurred a great number of experimental studies which present evidences of the benefits of magnetic treatment on many occasions. Some eye-catching proto-industrial examples ever reported include: the enhancement of oil recovery[l] and prevention of wax deposition[2-41 m petroleum production, transportation and refining; the improvement of fluidity of crude oils[571, and the d e d c a...

Petroleum-derived substances are complex and composed of aliphatic (normal-, iso-, and cycloparaffins), olefinic, and/or aromatic constituents. Approximately 400 of these complex substances were evaluated as part of the US Environmental Protection Agency voluntary High Production Volume (HPV) Challenge program. The substances were separated into 13 groups (categories), and all available data we...

The debutanizer column is an important unit operation in petroleum refining industries as it is the main column to produce liquefied petroleum gas as its top product and light naphtha as its bottom product. This system is difficult to handle from a control standpoint due to its nonlinear behavior, multivariable interaction and existence of numerous constraints on both its manipulated and state ...

Technological Change, Depletion and the U.S. Petroleum Industry*** A common claim in the nonrenewable resource literature is that improvements in technology may largely offset the effects of increasing scarcity over time. This study provides perhaps the first empirical evidence on this issue by analyzing the determinants of the average finding cost for additional petroleum in the U.S. over the ...

Gasification technologies meeting the definition proposed by the GTC offer an alternative process for the recovery and recycling of low-value, secondary materials by producing a more valuable commodity – syngas. The multiple uses of syngas (power production, chemicals, methanol, etc.) and the availability of gas clean-up technologies common to the petroleum refining industry make gasification o...

Increasingly, crudes of high acidity are observed in production of petroleum reserves. Naphthenic acids, which are generally cyclic and branched aliphatic carboxylic acids, are interfacially active and adsorb at water–oil interfaces to form monolayers, liquid crystalline films, and other colloidal structures. A serious challenge in petroleum production is the resulting stabilization of water-in...