This study presents the in vivo electrochemical monitoring of pH using boron doped diamond (BDD) microelectrode and silver needles for potential application in medical diagnosis. Accurate calibration curve for pH determination were obtained through in vitro electrochemical measurements. The increase induced in stomach pH by treatment with pantoprazole was used to demonstrate that it is possible...

Di-2-pyridyl ketone 2-furoylhydrazone (DPFH) has been examined as a sensitive spectrofluorimetric reagent for the determination of gallium. 4 rapid procedure for the fluorimetric determination of th i s ion at the 2-800 ng ml-1 level at pH 3.S4.1 (Aex 395 nm, he, 473 nm) has been established. The detection limit is 2 ng ml-1 and the relative standard deviation is 2.4% (40 p.p.b. of gallium). In...

Alpha-benzilmonoxime in sodium dodecylsulfate micellar media has been used for the spectrophotometric determination of cobalt at pH 9.0. The linear range of calibration is 0.05-1.50 microg cm(-3) of cobalt at 380 nm with molar absorptivity of 3.72 x 10(4) dm3 mol(-1) cm(-1), which is about 1.5-times greater than that of the alpha-benzilmonoxime extraction based method. The relative standard dev...