The paper investigates the physicochemical regularities (kinetics and isotherm) of phosphorus beryllium recovery by sorbents based on polyacrylonitrile (PAN) fiber Fe(OH)3 obtained various methods: PAN or pre-hydrolyzed with precipitation FeCl3 ammonia, using ready-made electrochemically generated Na2FeO4, treated an alkaline solution as well their comparison granular aluminum oxide. Langmuir, ...

A modified coaxial electrospinning process was used to prepare composite nanofibrous mats from a poly(methyl methacrylate) (PMMA) solution with the addition of different cellulose nanocrystals (CNCs) as the sheath fluid and polyacrylonitrile (PAN) solution as the core fluid. This study investigated the conductivity of the as-spun solutions that increased significantly with increasing CNCs addit...

(3-(tert-butylperoxy)propyl) trimethoxysilane (TBPT), is a tailor-made new style silane coupling agent with peroxide group, which have ability of initiating polymerization. This study used TBPT to generate free radical, and initiated the polymerization of acrylonitrile (AN), thereby forming polyacrylonitrile (PAN) in two approaches, thermal initiation system and redox initiation system. Meanwhi...

Ordered mesoporous carbon/iron oxide composites were prepared by cooperative self-assembly of poly(tbutyl acrylate)-block-polyacrylonitrile (PtBA-b-PAN), which contains both a carbon precursor block and a porogen block, and phenol-functionalized iron oxide nanoparticles (NPs). Because of the selective hydrogen bonding between the phenol-functionalized iron oxide NPs and PAN, the NPs were prefer...

We studied the suitability of in vitro dialysis with polyacrylonitrile (PAN) membranes to remove small amounts of interleukin-1 beta (IL-1 beta) and tumor necrosis factor (TNF) from plasma to be used as diluent for the standards in radioimmunoassays (RIA). Incubation of PAN membrane fragments with radiolabeled IL-1 beta or TNF yielded a significant binding of both cytokines to the membrane (per...

60Co γ-ray irradiation-initiated reversible addition–fragmentation chain transfer (RAFT) polymerization at room temperature with 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as the chain transfer agent was first applied to acrylonitrile (AN) polymerization, providing a “green” platform for preparing polyacrylonitrile (PAN)-based carbon fibers using an environment-friendly energy source. Various ...

Methanol crossover (MCO) significantly affects the performance of a direct methanol fuel cell (DMFC). In order to reduce its effect, this study presents in-house carbon nanofiber webs (CNWs) used as a porous methanol barrier for MCO control in a passive DMFC. The CNW is made from polyacrylonitrile (PAN) by using electrospinning and heat treatment. The impacts of PAN concentration and carbonizin...

Polyacrylonitrile (PAN) membranes have attracted much attention due to a variety of excellent characteristics, which include thermal stability nd tolerance to most solvents, atmosphere, bacteria and photo irradiation. Therefore, their exploitation also covers many fields, like pervaporation, ater treatment, enzyme immobilization, and hemodialysis. However, the relative poor hydrophilicity and b...

A facile, ultrasensitive, and selective sensor strip utilizing 4-amino-3-penten-2-one (fluoral-p) functionalized electrospun polyacrylonitrile (PAN) (PAN/fluoral-p) nanofibrous membranes has been successfully developed for naked-eye colorimetric assay of formaldehyde. The sensor strips presented a significant reflectance decreasing band at 417 nm which induced a vivid color change from white to...

Nanofibers with excellent activities in surface-enhanced Raman scattering (SERS) were developed through electrospinning precursor suspensions consisting of polyacrylonitrile (PAN), silver nanoparticles (AgNPs), silicon nanoparticles (SiNPs), and cellulose nanocrystals (CNCs). Rheology of the precursor suspensions, and morphology, thermal properties, chemical structures, and SERS sensitivity of ...