A dye-sensitized solar cell was constructed using a porphyrin photosensitizer and, in place of the usual iodide redox system, a solution in aniline solvent containing lithium perchlorate electrolyte, camphorsulfonic acid, and poly(ethylene oxide) copolymer. Irradiation generated polyaniline within the cell, initially following a proposed photoelectropolymerization mechanism, and eventually oper...

The synthesis characterization and conductivities of polyaniline/expanded vermiculite intercalated nanocomposite are presented in this paper. The conductive emeraldine salt form of polyaniline is inserted into the interlayer of expanded vermiculite to produce the nanocomposite with high conductivity. The structures and properties are characterized by transmission electron microscopy x-ray diffr...

We probed the charge transfer interaction between the amine-containing molecules hydrazine, polyaniline, and aminobutyl phosphonic acid and carbon nanotube field effect transistors (CNTFETs). We successfully converted p-type CNTFETs to n-type and drastically improved the device performance in both the ON- and OFF-transistor states, utilizing hydrazine as dopant. We effectively switched the tran...

Water dispersible nanofibrilar polyaniline (NF-PANI) provides a novel and direct route towards carbon nanotube water dispersions of high concentration. Carrying out the chemical synthesis of NF-PANI in the presence of carbon nanotubes (CNTs) results in an entirely nanostructured nanofibrilar polyaniline/carbon nanotube (NF-PANI/CNT) composite material that contains well segregated CNTs partiall...

Conducting filaments of polyaniline have been prepared in the 3-nanometer-wide hexagonal channel system of the aluminosilicate MCM-41. Adsorption of aniline vapor into the dehydrated host, followed by reaction with peroxydisulfate, leads to encapsulated polyaniline filaments. Spectroscopic data show that the filaments are in the protonated emeraldine salt form, and chromatography indicates chai...

A polyaniline-based conducting composite was prepared by oxidative polymerisation of aniline in a polyvinylchloride (PVC) matrix. The coherent free standing thin films of the composite were prepared by a solution casting method. The polyvinyl chloride-polyaniline composites exposed to 120 MeV ions of silicon with total ion fluence ranging from 10 to 10 ions/cm, were observed to be more sensitiv...

Polyaniline (PANI) has been shown to possess excellent catalytic activity toward oxygen reduction, however, this molecule may interfere with the electrochemical measurement of other targets when using a polyaniline modified platinum (PANI/Pt) electrode. In this study, we have demonstrated the considerable effects of dissolved oxygen on the sensing of hydrogen peroxide with the PANI/Pt electrode...

Polyaniline nanoparticles were prepared using oxidation polymerization in micro-emulsion system. Sodium dodecyl sulphate was used as a surfactant which dissolved in hydrochloric acid giving the micellar solution. Potassium persulphate was used as an oxidant. The produced particles were spherical in shape with an average diameter of 15 nm as detected from the transmittance electron microscope im...

This paper presents the processing and characterization of electromagnetic radiation absorbing paints and sheets based on magnetic and dielectric materials dispersed in polymeric matrices. Two different paint formulations containing carbonyl iron and/or polyaniline, using polyurethane as matrix, were prepared. Silicone sheets were also produced with polyaniline conducting polymer as filler. Mea...

In recent years, developments of inorganic–organic hybrid materials on nanometer scale have been receiving significant attention due to a wide range of potential applications and high absorption in the visible part of the spectrum and high mobility of the charge carriers [1-3]. Conductive polymer with polyaromatic backbone including polypyrrole, polythiophene, polyaniline, etc. The received a g...