A novel electrochemical sensing method was devised for the first time to detect plasma cortisol, a potential psychological stress biomarker, in human immunodeficiency virus (HIV)-positive subjects. A miniaturized potentiostat (reconfigured LMP91000 chip) interfaced with a microfluidic manifold containing a cortisol immunosensor was employed to demonstrate electrochemical cortisol sensing. This ...

The first-order reversal curve (FORC) method for analysis of systems undergoing hysteresis is applied to dynamical models of electrochemical adsorption. In this setting, the method can not only differentiate between discontinuous and continuous phase transitions, but can also quite accurately recover equilibrium behavior from dynamic analysis for systems with a continuous phase transition. Disc...

In experiments performed using graphite electrodes poised by a potentiostat (+200 mV versus Ag/AgCl) or in a microbial fuel cell (with oxygen as the electron acceptor), the Fe(III)-reducing organism Geothrix fermentans conserved energy to support growth by coupling the complete oxidation of acetate to reduction of a graphite electrode. Other organic compounds, such as lactate, malate, propionat...

This paper presents a low-power all-MOS deltasigma ADC specifically optimized for the potentiostatic biasing and amperometric read-out of electrochemical sensors. The proposed architecture reuses the dynamic properties of the sensor itself to implement a continuous-time mixed electrochemical delta-sigma modulator with minimalist analog circuits fully integrable in purely digital CMOS technologi...

In this work, the corrosion resistance of AISI 321 stainless steel is increased through. two-stage implantation oxygen ions and both aluminum boron together. During ion implantation, a modified layer with thickness about 200 nm formed, which affects properties material. The increase in confirmed by prolonged acid tests at pH 3.5 accelerated electrochemical using potentiostat. rate implanted sam...

Electrode effects on impedance spectra of cement pastes were investigated by two-, three-, and four-point measurements without a potentiostat over the frequency range 0,01 Hz–10 MHz. Electrode immittance effects arising from highly resistive/capacitive contacts cannot be fully corrected by nulling procedures, Two-point~measurements are much more susceptible to such effects than threeor four-poi...

High throughput electrochemical techniques are widely applied in material discovery and optimization. For many applications, the most desirable electrochemical characterization requires a three-electrode cell under potentiostat control. In high throughput screening, a material library is explored by either employing an array of such cells, or rastering a single cell over the library. To attain ...