Titanium dioxide (TiO2) attracts extensive attention due to its widespread technological and environmental applications. This study seeks to investigate the surface charging behavior of the two TiO2 polymorphs, anatase and rutile, using Flow Adsorption Microcalorimetry (FAMC). FAMC allows direct quantitative measurement of the heat of a surface reaction; these calorimetric heats are directly pr...

Iron-doped titanium dioxide nanoparticles, with Fe/Ti atomic ratios from 0% to 10%, were synthesized by flame spray pyrolysis (FSP), employing a single-step method. Ferrocene, being nontoxic and readily soluble in liquid hydrocarbons, was used as the iron source, while tetraisopropoxide (TTIP) precursor for TiO2. The general particle characterization phase description examined using ICP-OES, XR...

Considering the increasing demand for titania nanoparticles with controlled quality for various applications, the present work reports the up-scalable synthesis of size-controlled titanium dioxide nanocrystals with a simple and convenient thermal treatment route. Titanium dioxide nanocrystals with tetragonal structure were synthesized directly from an aqueous solution containing titanium (IV) i...

The development of different kinds of nanoparticles, showing different physico-chemical properties, has fostered their large use in many fields, including medicine. As a consequence, inorganic nanoparticles (e.g., metals or semiconductors), have raised issues about their potential toxicity. The scientific community is investigating the toxicity mechanisms of these materials, in vitro and in viv...

Titanium dioxide (TiO2) nanoparticles, have been routinely used in cosmetic and sunscreen applications, due to their ability absorb the UV spectrum. Nevertheless, one of main disadvantages has generation reactive oxygen species (ROS), especially hydroxyl radical, upon photoexcitation titania. In this work, we investigate TiO2 nanoparticles doped with 0.6–0.7% manganese (Mn), based more stable r...