The Soret effect, as it occurs in the diffusion of solutes in crystals, is analyzed using the principle of microscopic reversibility whereby an approach is developed for interpreting and computing Q*, the heat of transport. To compute the transport of energy during the diffusion jump process, and then Q*, the processes of thermal activation to the transition state and the decay from the transit...

In a series of publications, Kocherginsky and Gruebele presented systematic framework for chemical transport thermodiffusion to predict the Soret coefficients from thermodynamics. A macroscopic derivation Onsager reciprocal relations without recourse microscopic fluctuations or equations motion was also discussed. Their important contributions some confusions are

This article investigates numerically the effects of Hall current and rotation on radiating chemically reacting unsteady MHD natural convection flow past an accelerated infinite vertical permeable plate in presence Soret Dufour effects. The dimensionless coupled non-linear governing partial differential equations problem are solved by employing finite element method. influence various physical ...

Absorption spectra of several free base triarylcorroles were investigated by MCD spectroscopy. The MCD spectra exhibit unusual sign-reverse (positive-to-negative intensities in ascending energy) features in the Soret- and Q-type band regions, suggesting a rare ΔHOMO < ΔLUMO relationship between π and π* MOs in the corrole core.

The influences of thermal radiation, Heat Generation and Soret–Dufour on the boundary layer flow Micropolar Walters-B non-Newtonian fluid with MHD heat mass transfer are investigated, formulated model resulted to set partial differential equations (PDEs). PDEs were simplified using suitable similarity variable obtain total eqautions. transformed solve by employing spectral homotopy analysis met...

We have prepared and isolated the peptide fragments coded for by the three exons of the human beta-globin gene, using the arginine-specific protease clostripain (EC 3.4.22.8). The region encoded by the central exon (amino acid residues 31-104) contains an arginine at position 40. This site was less susceptible to cleavage than the two sites that correspond to the exon-intron boundaries, and the...