From magnetic resonance imaging to cancer hyperthermia and wireless control of cell signaling, ferrite nanoparticles produced by thermal decomposition methods are ubiquitous across biomedical applications. While well-established synthetic protocols allow for precise control over the size and shape of the magnetic nanoparticles, structural defects within seemingly single-crystalline materials co...

Thermolysis of a toluene solution containing [Fe3(CO)9(μ3-E)2] (E = S or Se) and [M(L)(CO)3(C CPh)], M = Mo or W, resulted in coupling of co-ordinated acetylide ligands with and without CO and formation of mixed-metal clusters [M2Fe3(L)2(CO)6(μ3-E)2{μ-CC(Ph)C(Ph)C}] (L = η-C5Me5, M = Mo, E = S 1 or Se 2; M = W, E = S 3 or Se 4; M = W, E = Te 5; L = η-C5H5, M = Mo, E = S 6 or Se 7; M = W, E = S ...

The processes of oxidative thermolysis bismuth tartrates [Bi(NO3)(C4H4O6)]·3H2O and BiC4H3O6·H2O precipitated from nitrate solutions was studied by the methods X-ray diffraction, thermal analysis, IR spectroscopy chemical analysis. staging transformation determined. Morphological studies initial precursors final products their transformations were carried out. expediency obtaining fine-crystal ...

The synthesis of germanium nanoparticles has been carried out, thanks to the design of novel aminoiminate germanium(II) precursors: (ATI)GeZ (with Z = OMe, NPh2, and ATI = N,N'-diisopropyl-aminotroponiminate) and (Am)2Ge (Am = N,N'-bis(trimethylsilyl)phenyl amidinate). These complexes were fully characterized by spectroscopic techniques as well as single crystal X-ray diffraction. The thermolys...

Vapour thermolysis processes of copper(I1) bis-chelate complexes with different p-diketones in the 160640°C temperature range were studied by using the high-temperature source of a molecular beam with mass spectrometric recording of the gas phase composition directly at the outlet from the thermal reactor. Schemes of a heterogeneous decomposition of these compounds vapour were suggested on the ...

AIM The aim of this study was to investigate in vitro the utility of biologically compatible, nontoxic and cell-specific targetable hydrogel nanoparticles (NPs), which have Coomassie® Brilliant Blue G dye (Sigma-Aldrich, MO, USA) covalently linked into their polyacrylamide matrix, as candidates for photothermal therapy (PTT) of cancer cells. MATERIALS & METHODS Hydrogel NPs with Coomassie Bri...

BACKGROUND The coordination chemistry of cadmium(II) with diamine ligands is of particular interest. The most common structure around cadmium(II) center in their complexes is tetrahedral, that is due the octet rule obeyed. Nevertheless, five and six-coordinated complexes are also well known. Now a day, many cadmium(II) complexes with chelate ligands were synthesized for their structural or appl...