Understanding the earliest molecular events during nucleation of the amyloid aggregation cascade is of fundamental significance to prevent amyloid related disorders. We report here an experimental kinetic analysis of the amyloid aggregation of the N47A mutant of the α-spectrin SH3 domain (N47A Spc-SH3) under mild acid conditions, where it is governed by rapid formation of amyloid nuclei. The in...

in this work, experimental kinetics data of methane hydrate decomposition at temperatures ranging from 272.15 to 276.15 k and at pressures ranging from 10 to 30 bars were modeled by using chemical affinity. this model proposed a macroscopic model which is independent of any intermediate mechanism like heat or mass transfer. the results show there is good agreement with experimental data. also t...

The mechanism for the formation of biomimetic model cell membranes consisting of bilayers composed of alkanethiols and phospholipids was probed with a kinetic study using surface plasmon resonance. The kinetics of formation of a monolayer of phospholipid from vesicles in solution onto a hydrophobic alkanethiol monolayer is described by a model that takes into account the lipid concentration, di...

In this research, Graphene Oxide- Gold nanoparticles (AuNP/GO) were easily fabricated by a redox reaction between GO and chloroauric acid without using any additional reductant and then used to stabilize Pickering emulsions. (AuNP/GO) was investigated by FT-IR spectroscopy. The changes of parameters such as contact time, pH, Amoxicillin initial concentration and temperature were tested and inve...

Removal of fluoride ions was investigated using a new adsorbent of yttrium alginate biocomposite (YALG). Effect of various parameters such as pH, contact time, initial concentration of fluoride ions and temperature on the sorption capacity of adsorbent was studied. Performing a mathematical assessment of fluoride sorption, isotherm and kinetics models including Freundlich & Langmuir isotherms a...

Field quantitative estimation of reaction kinetics is required to enhance our understanding of biogeochemical reactions in aquifers. We extended the analytical solution developed by Haggerty et al. (1998) to model an entire 1st order reaction chain and estimate the kinetic parameters for each reaction step of the denitrification process. We then assessed the ability of this reaction chain to mo...

An amended kinetic model for the self-assembly of empty capsids of brome mosaic virus is proposed. The model has been modified to account for a new feature in the assembly kinetics revealed by time-course light scattering experiments at higher temporal resolution than previously attempted. To be able to simulate the sharp takeoff from the initial lag phase to the growth phase in the kinetic cur...

An attempt has been made in this paper to investigate the effect of particle size distribution on coal flotation kinetics. The effect of particle size (Ps) on kinetics constant (k) and maximum theoretical flotation recovery (RI) was investigated while other operational parameters were kept constant. The relationship between flotation kinetics constant and theoretical flotation recovery with par...

Ginger waste material (GWM) has been utilized as adsorbent for removal of hazardousPatent Blue VF (PBVF) dye from aqueous solution. Batch adsorption experiments wereperformed as a function of pH, contact time, dye concentration, adsorbent dose and temperature.The optimum pH required for the maximum adsorption was found to be 2. The experimentalequilibrium adsorption data were tested using Langm...