A crackand pinhole-free composite membrane consisting of an a-alumina support and a modified y-alumina top layer which is thermally stable up to 1100°C was prepared by the sol-gel method. The supported thermally stable top layer was made by dipcoating the support with a boehmite sol doped with lanthanum nitrate. The temperature effects on the microstructure of the (supported and unsupported) La...

b1-xlaxfeo3 (x = 0.0, 0.025) crystallites were prepared by chemical solution route. xrd analysis confirmed the phase formation of the materials. thermal characterization was done by dsc-tga to confirm crystallization and thermal behavior for phase development. morphological studies by fesem showed the agglomerated nature of the ferrite and edx analysis confirmed the degree of doping. ftir studi...

We use the idea of Wigner probability distribution (WPD) in a reduced scattering phase space (RPS) for elastic cross-section, with help Tight-Binding (TB) numerical procedure allowing us to consider anisotropic quantum effects, phenomenologically predict several phases these two novel unconventional superconductors. Unlike our previous works pieces evidences that compounds are unitary strong re...

Laser action has been demonstrated in chalcogenide glass microsphere. A sub millimeter neodymium-doped gallium lanthanum sulphide glass sphere was pumped at 808 nm with a laser diode and single and multimode laser action demonstrated at wavelengths between 1075 and 1086 nm. The gallium lanthanum sulphide family of glass offer higher thermal stability compared to other chalcogenide glasses, and ...

The purpose of this work is to study the effect lanthanum (La) concentration on phase formation, conductivity, and thermophysical properties perovskite-like strontium ferrite ceramics. At same time, key difference from similar studies possibility obtaining two-phase composite ceramics, presence various phases in which will lead a change structural, strength, conductive properties. To obtain cer...

Titanium-doped gallium lanthanum sulfide (Ti:GLS) and gallium lanthanum oxysulfide (Ti:GLSO) glasses have an absorption band at 500–600 nm that cannot be fully resolved because of its proximity to the band edge of the glass. At concentrations 0.5% a shoulder at 980 nm is observed in Ti:GLS but not in Ti:GLSO. The emission spectra of Ti:GLS and Ti:GLSO both peak at 900 nm with lifetimes of 67 an...

We explore a number of novel effects near the orbital-order phase transition in a half-doped manganite, Pr0.5Ca0.5MnO3. To probe the unusual short-range orbital order in this system, we have performed coherent soft x-ray resonant scattering measurements in a Bragg geometry to measure dynamics. Near the transition temperature, we observe a small fluctuating component in the scattered signal that...

Strontium doped lanthanum cobalt ferrite (LSCF) is a widely applied electrocatalyst for the oxygen reduction reaction (ORR) in solid-oxide fuel cells (SOFCs) operated at intermediate temperatures. Sr surface segregation in long-term operation has been reported to have contradicting effects that either degrade or improve the reaction. Thus, it is critical to understand the mechanism of surface S...

Ionic transport dynamics underpins the functionality of most energy storage and conversion technologies. Yttrium-doped barium zirconate (Y-BZO) has attracted attention as a promising electrolyte for proton-conducting solid oxide fuel cells (PC-SOFCs), which stems from its high proton conductivity and excellent chemical stability at intermediate temperatures (400-700°C) [1]. The Grotthuss mechan...