Grafting terminally functionalized polypropylene (PP) to nanofillers provides well-defined PP-based nanocomposites plausibly featured with a physical cross-linkage structure. In this paper, a series of PP-grafted silica nanoparticles (PP-g-SiO2) were synthesized by varying the number of grafted chains per silica particle, and influences of the number and the molecular weight of grafted chains w...

In this work membrane (proton exchange membrane) by using the blend polymers (polyethersulfone (PES), Expandable polystyrene (EPS), polyvenylidinefluride polymer (PVDF)) were prepared. This was modified adding organic sulfonic acid to solution precasting process, and sulfonated dipping it in diluted sulfuric (H2SO460%) post casting process. The sulfonation confirmed via FTIR spectra. characteri...

Recently, H2O2 is drawing growing interest in green chemistry 15 because it acts as direct and environmental benign oxidant in organic synthesis [2] and because its high cost limits the use for the production of bulk organic chemicals. The synthesis of hydrogen peroxide by direct reaction between H2 and O2 is a very attractive alternative to traditional anthraquinone 20 process. Direct synthesi...

a mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using cro3 in the presence of sulfonic acid functionalized ordered nanoporous na+-montmorillonite (sanm) and under solvent-free conditions is reported. all reactions were performed at room temperature in high to excellent yields. ease of the p...

The cysteine residues in the active sites of certain proteins, including peroxiredoxin (Prx), Parkinson’s disease protein DJ-1, and glyceraldehyde-3-phosphate dehydrogenase (GAPDH), are more readily oxidized to sulfenic acid (Cys-SOH) than are other cysteines because of their environment. The unstable sulfenic acid undergoes further hyperoxidation to sulfinic (Cys-SO2H) and sulfonic (Cys-SO3H) ...

A simple procedure afforded novel spiroacenaphthylene derivatives in high yields at room temperature from acenaphthenequinone, malononitrile, and phenol derivatives using amino-functionalized silica (SBA-Pr-NH2) as a heterogeneous efficient solid base catalyst. Using SBA-Pr-NH2 in the current procedure presents several advantages, such as a simpler procedure, shorter reaction times, facile synt...

New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Brønsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in solvent extraction studies.

Functionalized mesoporous silica has applications in separations science, catalysis, and sensors. In this work, we studied the fundamental interactions of trivalent cations with functionalized mesoporous silica. We contacted trivalent cations of varying ionic radii with N-[5-(trimethoxysilyl)-2-aza-1-oxopentyl]caprolactam functionalized mesoporous silica with the aim of probing the binding mech...

In this paper, we investigated the functional imaging properties of magnetic microspheres composed of magnetic core and CdTe quantum dots in the silica shell functionalized with folic acid (FA). The preparation procedure included the preparation of chitosan-coated Fe3O4 nanoparticles (CS-coated Fe3O4 NPs) prepared by a one-pot solvothermal method, the reaction between carboxylic and amino group...

A study of silica and iron recovery from the iron ore concentration tailing is presented. The residue is composed of 40.1% Fe, 33.4% SiO2, 8.31% Al2O3, 0.08% P, and 0.34% MnO. The developed process of silica and iron recovery consisted of size classification, magnetic separation, and removal of impurities by leaching. A concentration of SiO2 from 33.4% to 67.0%, with 60.0% of mass reduction, wa...