An all-fiber isolator with 17 dB optical isolation is demonstrated. The fiber Faraday rotator uses 56 wt. % terbium (Tb)-doped silicate fiber, and the fiber polarizers are Corning SP1060 single-polarization fiber. The effective Verdet constant of the Tb-doped fiber is measured to be -24.5+/-1.0 rad/(Tm) at 1053 nm, which is 20 times larger than silica fiber and 22% larger than previously report...

The emission spectra of luminescent trivalent europium (Eu3+) and terbium (Tb3+) complexes were measured using a microscope laser Raman spectrometer with a doubled Nd:YAG laser (532 nm) and an Ar laser (488 nm). Excitation at 532 and 488 nm corresponded to wavelengths of the 7F1 --> 5D1 band of Eu3+ and the 7F6 --> 5D4 band of Tb3+, respectively. The Eu3+ and Tb3+ complexes were discriminated b...

Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented. ∗Corresponding author. Email address: [email protected] (M. Thoennessen...

A facile nonlithographic method for expedient fabrication of microfluidic devices of poly(dimethylsiloxane) is described. Positive-relief masters for the molds are directly printed on smooth substrates. For the formation of connecting channels and chambers inside the polymer components of the microfluidic devices, cavity-forming elements are adhered to the surfaces of the masters. Using this no...

The formation of self-assembly complexes between the ligands 1 (SS) and 2 (RR) and terbium or europium was undertaken and shown (using various spectroscopic titrations) to give rise to the exclusive formation of 2:1 (L:Ln) stoichiometry and not the anticipated 3:1 stoichiometry.

Reaction of [Tb(III)(DMSO)(8)](CF(3)SO(3))(3) with a resorcinarene cavitand substituted by four -CH(2)P(O)Ph(2) pendant arms afforded an infinite 1D inorganic polymer, in which the consecutive resorcinarene units are linked through two terbium strands, this connection involves pairs of phosphoryl groups occupying adjacent positions of the resorcinarene units.

Luminescent europium and terbium complexes and a mixed Eu(III)-Tb(III) complex were prepared, each with three macrocycles coordinating to a single lanthanide ion to form a trimetallic system, and can be used for the ratiometric sensing of anions in the case of the mixed complex.

Z. Naturforsch. 54 b, 1277-1282 (1999); received May 27, 1999 Intermetallic Compounds, Crystal Structure, Close Packed Layers The new compounds GdReaAlio and TbRe.Alio were obtained in well-crystallized form by reaction of the elemental components with an excess of aluminum after dissolving the matrix in hydrochloric acid. They crystallize with a new structure type which has been determined for...

Terbium at submillimolar concentrations appears to bind to the calcium site of apo bovine a-lactalbumin and stabilizes the N conformation (fluorescence criterion; Kronman, M. J., Sinha, S., and Brew, K. (1981) J. Biol. Chem. 256, 8582-8586). At millimolar concentrations however, it binds additionally to a low affinity site of both apoand calcium-liganded protein, inducing a time-dependent confo...