نتایج جستجو برای: thermochemical equilibrium
تعداد نتایج: 132301 فیلتر نتایج به سال:
A Monte Carlo–probability density function (pdf) method based on a Lagrangian particle technique to calculate the transported pdf of the thermochemical (scalar) properties has been implemented in the finite volume code KIVA-3 to model three-dimensional premixed transient combustion in a two-stroke engine. The main advantage of the pdf method is that chemical reactions in turbulent flows can be ...
This study evaluated the possibility of pretreating selected solid fraction of an anaerobic digester treating food waste to lower the hydraulic retention time and increase the methane production. The study investigated the effect of different pretreatments (thermal, chemical, thermochemical and enzymatic) for enhanced methane production from cottage cheese. The most effective pretreatments were...
The formation of cobalt nanoclusters from polynuclear Co-alkyne species can be directed by multivalent calixarene ligands; thermochemical studies of Con-calixarenes reveal the influence of multivalency in prenucleation and postnuclear growth processes.
Today there is a worldwide interest in the use of biomass as an environmental friendly renewable energy source. The depletion of fossil oil reserves, constant uncertainties as far as price is concerned, unsecured supplies, and environmental pollution are among the many energy problems, when the use of fossil fuels are considered. Greenhouse effect and its consequences on climate change is one o...
Organophosphorous compounds are involved in many toxic compounds such as fungicides, pesticides, or chemical warfare nerve agents. The understanding of the decomposition chemistry of these compounds in the environment is largely limited by the scarcity of thermochemical data. Because of the high toxicity of many of these molecules, experimental determination of their thermochemical properties i...
Solar-driven thermochemical water splitting using non-stoichiometric oxides has emerged as an attractive technology for solar fuel production. The most widely considered oxide for this purpose is ceria, but the extreme temperatures required to achieve suitable levels of reduction introduce challenges in reactor design and operation, leading to efficiency penalties. Here, we provide a quantitati...
This work investigates the potential of coconut shell for air-steam gasification using thermodynamic equilibrium model. A thermodynamic equilibrium model considering tar and realistic char conversion was developed using MATLAB software to predict the product gas composition. After comparing it with experimental results the prediction capability of the model is enhanced by multiplying equilibriu...
In this report the thermochemical conversion of Sm2O3 to SmCl3 using AlCl3 in LiCl-KCl melt at 773 K is discussed. The final product was a mixture SmCl3, Al2O3, unreacted and chloride melt. electrochemical attributes analyzed with cyclic voltammetry (CV) square wave (SWV). crystallographic phases were studied X-ray diffraction (XRD) technique. major chemical optimized by varying effective param...
This paper presents and tests a previously unrecognized mechanism for driving a replicating molecular system on the prebiotic earth. It is proposed that cell-free RNA replication in the primordial soup may have been driven by self-sustained oscillatory thermochemical reactions. To test this hypothesis, a well-characterized hydrogen peroxide oscillator was chosen as the driver and complementary ...
[1] The resolution operator R is a critical accompaniment to tomographic models of the mantle. R facilitates the comparison between conceptual three-dimensional velocity models and tomographic models because it can filter these theoretical models to the spatial resolution of the tomographic model. We compute R for the tomographic model S20RTS (Ritsema et al., 1999, 2004) and two companion model...
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