In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N'-(2-hydroxy-benzil-idene)aceto-hydrazide and copper(II) chloride, the Cu(II) atom is coord-inated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal s...

In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octa-hedral geometry. The Sn-Cl bond [2.366 (2) Å] trans to nitro-gen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N-Sn-N angle [76.19 (11)°] is smaller than the O-Sn-N angle [87.89 (10)°] i...

The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy-droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa-hedral geometry. In the cry...

Schiff-base ligands are potential anti-cancer, anti-bacterial and anti-viral agents and this activity tends to increase in metal(II) Schiff-base complexes. Some oxindole-Schiff base copper(II) complexes have shown potential antitumor activity towards deferent cells, inducing apoptosis in a process modulated by the ligand. Here, six novel copper(II) complexes with schiff base ligands were isolat...

High throughput screening (HTS) of a 205 member Schiff base salicylaldimine ligand library derived from salicylaldehydes bearing bulky ortho-substituents, i.e., 9-anthracenyl, 1,4,5,8-tetramethylanthracenyl or triptycenyl, reacted in-situ with (p-tolyl)CrCl2(thf)3, identified two new classes of highly active chromium based systems for the oligomerization and polymerization of ethylene, respecti...

Helmut Paulus Institut für Physikalische Chemie, Abteilung Strukturforschung, Technisch© Hochschule Darmstadt, Petersenstraße 20, D-0100 Darmstadt Z. Naturforsch. 37b, 1266-1273 (1982); received March 31, 1982 X-ray, UV/VIS Spectra, Tridentate ONN Schiff Base, Copper(II) Complexes, Palladium(II) Complexes The tridentate mono-basic Schiff base N-(2-diethylaminoethyl)salicylaldimine =Hsalen-NEt2 ...

Reactions of MnX(2) meltsalt (X = Cl and ClO(4)) and a quinquedentate Schiff base ligand together with its coligand azides in MeOH produced the unprecedented assembly of novel octa- and hexadecanuclear manganese clusters containing two and four alternant tetrahedral Mn(III)(3)Mn(II) cores bridged by Schiff base ligands and versatile azides groups. The magnetic measurements on both compounds ind...

A new Schiff base ligands (H2L -H2L 3) was synthesized by the condensation reaction of 4-acyl pyrazolones and 2-benzothiazolyl thiosemicarbazide. The ruthenium(II) Schiff base complexes were prepared by the interaction of the ligands with [RuHCl(CO)(EPh3)2(B)] (E=P/As; B=PPh3/AsPh3/py). They were characterized by elemental analysis, IR, UV-vis, 1H, 13C, and 31P NMR spectral data. The interactio...

In the title dinuclear complex, [NiPr(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol ligands, forming a slightly distorted octa-hedral geometry. The Pr(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a dist...