We report on a novel method based on intracavity spontaneous mode locking to precisely measure the group refractive indices and temperature dependence of refractive index of Nd:YVO(4) crystal at the wavelength of 1064 nm. All the experimental results are found to agree very well with the most recent measured values. We also confirm that the developed method is applicable to measuring the group ...

The 6-amino-6-methyl-1,4-diazepine framework is a readily available neutral 6-electron ligand moiety, suitable to support cationic group 3 metal alkyl catalysts; it also provides convenient access to tri- and tetradentate monoanionic ligand derivatives.

A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1'-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.

A theoretical investigation of the ring-opening polymerization (ROP) mechanism of rac-lactide (LA) with an yttrium complex featuring a N-heterocyclic carbine (NHC) tethered moiety is reported. It was found that the carbonyl of lactide is attacked by N(SiMe3)2 group rather than NHC species at the chain initiation step. The polymerization selectivity was further investigated via two consecutive i...

Two very rapid yttrium initiators for lactide polymerisation are reported; the nuclearity (monomer vs. dimer) of the initiator controls the stereochemistry of the polylactide produced.

fro11 1 pegmatite in Cardiff township, Haliburton County, Ontario. Found as dark reddish brown to brownish black anhedral masses. Hardneis B$, specific gravity 8,08. Metamict; isotropic with n near 1.630. when the mineral is heated at 925" i the n increases to about 1.640 and the specific gravity to 8.20. At high temperatures the mineral decomposes before it recrystallizes and r-ray difiraction...

The location of the hole and acid proton in neutral nonprotonated and protonated mixed (phthalocyaninato)(porphyrinato) yttrium double-decker complexes, respectively, is studied on the basis of density functional theory (DFT) calculations on the molecular structures, molecular orbitals, atomic charges, and electronic absorption and infrared spectra of the neutral, reduced, and two possible prot...