Zerovalent iron nanoparticle (nZVI) technology has been found to be promising and effective for soil groundwater remediation. This paper shows the results of two batch tests (Test A Test B) carried out assess capacity nZVI remediate arsenic (As)-contaminated water. A, performed with batches tap water contaminated by arsenic, a concentration equal 10 mg ? L?1, showed significant reduction As con...

Biological reduction of perchlorate by autotrophic microorganisms attached to zerovalent iron (ZVI) was studied in flow-through columns. The effects of pH, flow rate, and influent perchlorate and nitrate concentrations on perchlorate reduction were investigated. Excellent perchlorate removal performance (> or = 99%) was achieved at empty bed residence times (EBRTs) ranging from 0.3 to 63 h and ...

The gas-phase dissociation of perchloroethene (PCE), trichloroethene (TCE), and cis-dichloroethene (cis-DCE) on zerovalent iron Fe(110) was investigated using periodic density functional theory (DFT) with the generalized gradient approximation (GGA) and climbing image nudged elastic band method (CI-NEB). Activation energies and dechlorination rate constants for reductive beta-elimination of the...

1,4-dioxane is an emerging contaminant that was used as a corrosion inhibitor with chlorinated solvents. Metal-activated persulfate can degrade dioxane but reaction kinetics have typically been characterized by a rapid decrease during the first 30 min followed by either a slower decrease or no further change (i.e., plateau). Our objective was to identify the factors responsible for this plateau...

This study synthesized the wheat straw biochar-supported nanoscale zerovalent iron (BC-nZVI) via in-situ reduction with NaBH4 and biochar pyrolyzed at 600°C. Wheat straw biochar, as a carrier, significantly enhanced the removal of trichloroethylene (TCE) by nZVI. The pseudo-first-order rate constant of TCE removal by BC-nZVI (1.079 h-1) within 260 min was 1.4 times higher and 539.5 times higher...

Objective: Growing resistance of microorganisms to potent antibiotics has renewed a great interest towards investigating bactericidal properties of nanoparticles and their nanocomposites as an alternative. Therefore, the present study has been carried out to investigate and compare the antibacterial properties of copper (Cu) and zerovalent iron (Feo) nanoparticles. Methods: Nanoparticles were s...

Zerovalent Nb(0) and Ta(0) nanoparticles are prepared via a one-pot, liquid-phase synthesis for the first time. This is challenge due to basic highly oxophilic character of both metals.