Administration (LRCVES/CMA), National Satellite Meteorological Center, China Meteorological Administration, Beijing 100081,China (2) State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), The Institute of Atmospheric Physics, CAS, Beijing 100029, China (3) Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium ABSTRACT In this study, SCIAMACHY/...

C6H5SO2 radicals were produced upon irradiation of three flowing mixtures: C6H5SO2Cl in N2, C6H5Cl and SO2 in CO2, and C6H5Br and SO2 in CO2, with a KrF excimer laser at 248 nm. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record the time-resolved infrared (IR) absorption spectra of reaction intermediates. Two transient bands with origins a...

Since 2004, the satellite-borne Ozone Mapping Instrument (OMI) has observed sulphur dioxide (SO2) plumes during both quiescence and effusive eruptive activity at Soufrière Hills Volcano, Montserrat. On average, OMI detected a SO2 plume 4-6 times more frequently during effusive periods than during quiescence in the 2008-2010 period. The increased ability of OMI to detect SO2 during eruptive peri...

Greenhouse gas emission limits are a major source of technical and policy uncertainty for electric power industry professionals. This paper tries to reduce some of this uncertainty by investigating the main forces that were responsible for the productivity gains made by the electric power sector with respect to SO2 emissions under the US SO2 cap and trade program. The SO2 cap and trade experien...

Thermodynamics of reactions of vanadium oxide clusters with SO2 are studied at the BPW91/LANL2DZ level of theory. BPW91/LANL2DZ is insufficient to properly describe relative V-O and S-O bond strengths of vanadium and sulfur oxides. Calibration of theoretical results with experimental data is necessary to compute reliable enthalpy changes for reactions between VxOy and SO2. Theoretical results i...

−Poly-Ethylene Glycol (PEG) 300+H2O solutions (PEGWs) has been used as a promising medium for the absorption of SO2. We investigated the UV, FTIR, 1H-NMR, and fluorescence spectra in the absorption processes of SO2 in PEGWs to present an important absorption mechanism. Based on the spectral results, the possibility of intermolecular hydrogen bond formation by hydroxyl oxygen atom in the PEG mol...

[1] Severe smog episodes over China in January 2013 received worldwide attention. This air pollution was distinguished by heavy loadings of fine particulate matter and SO2. To characterize these episodes, we employed the Ozone Mapping and Profiler Suite, Nadir Mapper (OMPS NM), an ultraviolet (UV) spectrometer flying on the Suomi National Polar-orbiting Partnership (SNPP) spacecraft since Octob...

In this work, we investigated the performance of Ag-alumina catalysts for the SCR of NO with methane in gas streams with a high concentration of SO2, typical of coal-fired power plant flue gas. Agalumina catalysts were prepared by co-gelation and nitric-acid leaching was used to remove weakly bound silver species from the catalyst surface [1, 2]. We found that SO2 has a dramatic inhibitory effe...

Honeycomb cordierite-based Mn–Ce/Al2O3 catalysts were prepared by the impregnation method and used for low-temperature selective catalytic reduction (SCR) of NOx with NH3, with and without SO2 and/or H2O in a homemade fixed-bed tubular reactor. The catalyst reached nearly 80% NOx conversion at 100 ◦C in the absence of SO2. However, SO2 reduces the catalytic activity (80% to 72%) of the honeycom...