A classification of kinetics of metalloporphyrin formation is presented according to the composition of the activated complex involved in the reaction. In the reaction of large metal ions, such as mercury(II) and cadmium(II) with porphyrins, these metal ions can not fit into the porphyrin nucleus and they are out—of-plane in the metalloporphyrin. In this case the reaction is relatively fast and...

background: the widespread use of toluene and its consequent adverse effects on health and specially its chronic effects on the central nervous system has resulted in many studies being carried out on the methods that can control and reduce toluene vapors in the airflow. the objective of this study is to assess the effectiveness of the catalytic ozonation process in the removal of toluene from ...

in this work, the removal of copper from an aqueous solution by granular activated carbon (gac) in the presence of competitor ions was studied. a batch adsorption was carried out and different parameters such as ph, contact time, initial copper concentration and competitor ions concentration were changed to determine the optimum conditions for adsorption. the optimum ph required for maximum ads...

abstract introduction: due to environmental and human health concerns related to humic acid (ha), mainly leading to disinfection by-products creation, removal or reduction of this matters is a necessary for drinking water suppliers. based on resistive economy map road and move to self-sufficiency, it is necessary to produce our need in water treatment industry. one of the main consumed material...

feasibility of methanolic wastes treatment containing chlorophenol in experimental uasb reactors i.e. r-i and r-ii working side by side constantly for a couple of almost 32 weeks were studied. uasb reactor r-i was initiated by utilizing the digested sludge alone, whereas, the uasb reactor r-ii was startedup by adding an activated carbon of an effective size 1.5-2.5mm to the digested sludge with...

in the present study, removal of dibenzothiophene (dbt) from model oil (n-hexane) was investigated using magnetic activated carbon (mac) nano-composite adsorbent. the synthesized nano-composite was characterized by ft-ir, fe-sem, bet and vsm techniques. the mac nano-composite exhibited a nearly superparamagnetic property with a saturation magnetization (ms) of 29.2 emu g-1, which made it desira...

cellulose wastes of a wood and paper factory were used to produce activated carbon. several chemical agents under various conditions were used for production of activated carbon and hence their adsorption properties have been evaluated. in addition the effect of process parameters such as raw material, chemical agent concentration, impregnation ratio, carbonization temperature, carbonization ti...

background: industrial development has caused the release of various pollutants including heavy metals into the environment. these toxic compounds are extremely dangerous to living beings and the environment due to their non-biodegradability, severe toxicity, carcinogenicity, the ability to be accumulated in nature and the ability to contaminate groundwater and surface water. the aim of the pre...

Carbon activated powdered was prepared from activated carbon derived from olive stone. Then byusing the surface methodology, many parameters such as pH, furnace temperature (T), acid ratio,time of activation that affect on the qualities prepared activated carbon produced and its efficiencywere investigated. In addition, the adsorption of Congo Red onto the activated olive stone carbonactive was...