The fatigue properties of ultrathin protective coatings on silicon thin films were investigated. The cohesive and delamination fatigue properties of 22 nm-thick atomic-layered-deposited (ALD) titania were characterized and compared to that of 25 nm-thick alumina. Both coatings were deposited at 200 °C. The fatigue rates are comparable at 30 °C, 50% relative humidity (RH) while they are one orde...

Porous alumina was fabricated and optically characterized over a wide spectral range. Layers were formed electrochemically in oxalic acid solution from 10-mm-thick aluminum films evaporated onto silicon wafers. The layer formation was monitored with in situ spectroscopic ellipsometry in the visible and near-infrared wavelength range to accurately determine the thickness and dielectric functions...

The effect of alumina nanoparticles on the heat transfer performance of an oscillating heat pipe (OHP) was investigated experimentally. A binary mixture of ethylene glycol (EG) and deionized water (50/50 by volume) was used as the base fluid for the OHP. Four types of nanoparticles with shapes of platelet, blade, cylinder, and brick were studied, respectively. Experimental results show that the...

901 JAOCS, Vol. 80, no. 9 (2003) ABSTRACT: In this study it is shown that the epoxide derivative of oleic acid, methyl 9,10-epoxyoctadecanoate, is readily hydrolyzed to a diol when exposed to a commercial preparation of neutral alumina. Comparison of 1H and 13C NMR spectra of the diol with those of standards showed that the product was the threo isomer. When methyl 9,10-12,13-diepoxyoctadecanoa...

The reaction of Mo(CO)6 with thin films of dehydroxylated alumina grown on a Mo(1 0 0) substrate above 500 K is studied in ultrahigh vacuum using temperature-programmed desorption and Auger and X-ray photoelectron spectroscopies. This results in the formation of a molybdenum carbide that incorporates a small amount of oxygen, where MoC is formed initially, becoming closer to Mo2C as the Mo(CO)6...

It is known that the toughness of brittle ceramics can be improved significantly with the addition of hard platelets. In the present study, platelet-shape multilayer ceramic laminates are utilized as a toughening agent for alumina ceramics. They are prepared by laminating the BaTiO3-based ceramic tapes. Although the elastic modulus of the BaTiO3based platelets is lower than that of the alumina ...

Anodic porous alumina with duplex layers exhibits a voltage-induced switching effect and is a promising candidate for resistive random access memory. The nanostructural analysis of porous alumina is important for understanding the switching effect. We investigated the difference between the two layers of an anodic porous alumina film using transmission electron microscopy and electron energy-lo...

Methanol, formaldehyde, carbon monoxide, and propylene conversion were examined in a laboratory flow reactor over three base-metal containing alumina-supported palladium (Pd) catalysts in addition to Pd on y-alumina catalyst. The base metals were cerium, barium, and a combination of the two. Experiments were performed to determine the effect of air to fuel ratio on lightoff temperatures of vari...

Nanofabrication by self-organization methods has attracted much attention owing to the fact that it enables mass production without the use of expensive lithographical tools, such as an electron beam exposure system. Porous alumina can be fabricated electrochemically through anodic oxidation of aluminum by means of such a self-organization method, yielding highly ordered arrays of nanoholes sev...

Anodization techniques by alternating current (ac) are introduced in this review. By using ac anodization, laminated alumina films are fabricated. Different types of alumina films consisting of 50-200 nm layers were obtained by varying both the ac power supply and the electrolyte. The total film thickness increased with an increase in the total charge transferred. The thickness of the individua...