Nanostructured hybrids of graphene oxide and palladium were fabricated by means one-step solvent-free gas phase treatment with the aliphatic amines 1-octadecylamine 1,8-diaminooctane, followed in situ decoration liquid medium using chloride as precursor citric acid a mild environmentally friendly stabilizing reducing agent. The proposed synthesis method represents an eco-friendly alternative fo...

Iron concentrations in the ocean are low enough to limit the growth of marine microorganisms, which raises questions about the molecular mechanisms these organisms use to acquire iron. Marine bacteria have been shown to produce siderophores to facilitate iron(III) uptake. We describe the structures of a suite of amphiphilic siderophores, named the amphibactins, which are produced by a nearshore...

Although bioactive polymers such as cationic polymers have demonstrated potential as drug carriers and nonviral gene delivery vectors, high toxicity and uncontrolled, instantaneous cellular interactions of those vectors have hindered the successful implementation In Vivo. Fine control over the cellular interactions of a potential drug/gene delivery vector would be thus desirable. Herein, we hav...

Amphiphilic molecules (the word derives from the Greek αμφὶ φιλία, meaning “love on both sides”) are molecules which both love and hate water. They are formed by two parts with very different tastes, which are covalently bound together: one, the hydrophilic head, is polar or even ionized, and tends therefore to be close to the small, polar water molecules; the other, the hydrophobic tail, is us...

We describe the formation of amphiphilic polymeric assemblies via a three-step functionalization process applied to polypropylene (PP) nonwovens and to reference hydrophobic self-assembled n-octadecyltrichlorosilane (ODTS) monolayer surfaces. In the first step, denatured proteins (lysozyme or fibrinogen) are adsorbed onto the hydrophobic PP or the ODTS surfaces, followed by cross-linking with g...

α-Helical antimicrobial peptides (AMPs) generally have facially amphiphilic structures that may lead to undesired peptide interactions with blood proteins and self-aggregation due to exposed hydrophobic surfaces. Here we report the design of a class of cationic, helical homo-polypeptide antimicrobials with a hydrophobic internal helical core and a charged exterior shell, possessing unprecedente...

Hydrogen bonding between urea groups of amphiphilic tri-block copolymers considerably affects their self-assembly in water, which results in a strong modification of morphology and viscosity of aqueous solutions; the hydrogen bonding motif in these amphiphilic copolymers allows molecular recognition of small molecules with complementary hydrogen bonding units.

Nanofibrillated cellulose (NFC) was incorporated to reduced graphene oxide (rGO) for fabrication of multifunctional amphiphilic aerogels. The as-prepared amphiphilic aerogel showed excellent recoverability, superior absorption capacity for both organic solvents and water, and an electrical conductivity sensitive to compressive strain making it highly potential to be used as a pressure-responsiv...

Autofluorescent micelles were constructed via the self-assembly of amphiphilic molecules containing an intrinsic fluorophore. The amphiphilic molecule was an AIE-active luminogen without a conventional π-π conjugated structure. In this unconventional luminogenic system, the hydrogen-bonded amide groups were assigned as the emitting sources.