Linear free energy scaling relationships and volcano plots are common tools used to identify potential heterogeneous catalysts for myriad applications. Despite the striking simplicity and predictive power of volcano plots, they remain unknown in homogeneous catalysis. Here, we construct volcano plots to analyze a prototypical reaction from homogeneous catalysis, the Suzuki cross-coupling of ole...

Linear free energy scaling relationships and volcano plots are common tools used to identify potential heterogeneous catalysts for myriad applications. Despite the striking simplicity and predictive power of volcano plots, they remain unknown in homogeneous catalysis. Here, we construct volcano plots to analyze a prototypical reaction from homogeneous catalysis, the Suzuki cross-coupling of ole...

Marine seismic data from the Blake Outer Ridge offshore Florida show strong “bottom simulating reflections” (BSR) associated with methane hydrate occurence in deep marine sediments. We use a detailed amplitude versus offset (AVO) analysis of these data to explore the validity of models which might explain the origin of the bottom simulating reflector. After careful preprocessing steps, we deter...

OBJECTIVES The purpose of this study was to assess individual mechanisms of effort intolerance in patients with heart failure with preserved ejection fraction (HFpEF), heart failure with reduced ejection fraction (HFrEF), or normal cardiac function using combined echocardiography and cardiopulmonary stress testing. BACKGROUND Combined stress echocardiography and cardiopulmonary tests visualiz...