All-in-one: A new and general one-pot reaction sequence initiated by singlet oxygen that transforms simple furan substrates into complex nitrogen-bearing aromatic polycycles having all the structural features of a number of important natural products (for example, the erythrina alkaloids; see scheme, RB = rose Bengal) is reported. The reaction sequence itself uses mild conditions and has wide f...

The project presents an analysis of the vibrational behavior of a deep groove ball bearing with a structurally integrated force sensor. The miniaturized force sensor, accommodated within a slot on the bearings outer ring, provides online condition monitoring capability to the bearing. Analytical and finite element models are developed to predict the sensor output due to bearing dynamic load and...

A further step could be to develop multifunctional structures, or structures that carry loads and perform system functions. Multifunctional system technologies such as conformal load bearing antenna structures, structurally integrated energy storage/harvesting, mechanised structural systems for morphing vehicle geometry, integrated/distributed sensing and associated technologies form the basis ...

The electronic and structural properties of two tetrathiafulvalene derivatives bearing aromatic benzene rings are reported. Thin film transistors of these materials show p-type characteristics with comparable mobility values. It is found that the rigidification of the molecule is beneficial for reducing the reorganisation energy but also has an unfavorable impact on the electronic structure dim...

An unprecedented highly diastereoselective and enantioselective aldol reaction of α-alkyl azlactones and aliphatic aldehydes was achieved with cinchona alkaloid catalysts. To our knowledge, this reaction provides the first useful catalytic asymmetric access toward β-hydroxy-α-amino acids bearing alkyl substituents, which are structural motifs embedded in many natural products.

A novel class of pH-sensitive PEG lipids bearing acid-cleavable acetal linkages and short PEG chains have been synthesised and used in ternary vector formulations. The cleavage pH was influenced by structural components including the terminal PEG moiety and spacer length.

In this paper, the effectiveness of stiffness and damping of bearing is investigated on the natural frequencies of the rotor-bearing system. The rotor-bearing system consists of a shaft, two bearings and a disk between two bearings. Parallel spring-damper in horizental and vertical directions is considered for modeling the stiffness and damping of bearings. The gyroscopic effect is also conside...

development of the structural form is directly influenced by the architectural concern for aesthetic appeal. the architectural challenge is to create building forms that satisfy the functional requirements, yet are aesthetically and economically successful. the structural challenge is to create structural forms that accommodate the functional requirements while supporting the imposed loads as e...