Tertiary amine-modified corn starches were converted to their basic or hydroxide form and combined with carboxylated butadiene-acrylonitrile copolymer and butadiene-styrene-sulfonic acid polymer to produce ionically bonded filler-elastomer composites. An increasing percentage of the elastomer fraction in the starch-elastomer composite is insolubilized as the starch-to-elastomer ratio increases....

ZHIYUAN YANG, YANJUN TANG , JUNHUA ZHANG Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, 310018, China State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, China Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zheji...

1,3-Butadiene is an important industrial chemical used in the production of synthetic rubber and is also found in gasoline and combustion products. It is a multispecies, multisite carcinogen in rodents, with mice being the most sensitive species. 1,3-Butadiene is metabolized to several epoxides that form DNA and protein adducts. Previous analysis of 1,2,3-trihydroxybutyl-valine globin adducts s...

As a means to decrease the amount of waste tires and to re-use tire rubber for new tires, devulcanization of ground passenger car tires is a promising process. Being an established process for NR and EPDM, earlier work has shown that for ground passenger car tire rubber with a relatively high amount of SBR, a devulcanization process can be formulated, as well. This was proven for a laboratory-s...

Because these reactive sites are pendant (not part of the main backbone chain) there are no weak points on the main chain. This is unlike for example Natural Rubber or SBR, where these necessary reactive sites are along the main chain. This means that reactive entities in the atmosphere (for example Ozone, which is very aggressive) can easily attack and degrade these materials. This also explai...

mixing conditions of nbr/pvc nanocomposites such as mixing temperature, rotor speed and mixing time are determining parameters in rheological, mechanical and morphological properties of the compound. three levels were chosen for each parameter using design expert software via box-behnken method. the nanocomposite samples were melt-mixed in brabender internal mixer. the effect of various mixing ...

Synthetic rubber is commonly used in applications in which interaction with a polar matrix is beneficial, and the introduction of polar groups into the polymer can be used to improve this interaction. Styrenebutadiene rubbers and butadiene rubbers containing polar or reactive functionalities have been reported in the academic and patent literature, and select functionalized polymers are manufac...

In this work the effect of the γ-radiation dose on ageing of carbon black reinforced elastomeric materials was studied. The compounds based on natural rubber/chlorosulfonated rubber blend (NR/CSM) and butadiene acrylonitrile rubber/chlorosulfonated rubber blend (NBR/CSM) (50:50, w/w) with different loadings (0, 20, 40, 50, 60, 80 and 100 phr) of the filler with the average particle size of 40 n...