نتایج جستجو برای: chiral auxiliaries

تعداد نتایج: 38094  

2012
A. M. Zwicky

Wells and Local ( 1983) intend to propose a thoroughly pragmatics-based explanationfor the unacceptability ofcertain instances ofaccented injinitival to, have, and be in English, in reaction to Zwicky and Levin’s (1980) argumentsfor a constraint couched in syntactic terms. A comparison ofthe two accounts serves as the vehicle for a discussion ofseveral larger issues: choosing between theoretica...

Journal: :Journal of the American Institute of Electrical Engineers 1921

2001
Nello Paver

We study the D → σπ, D → ρπ, B− → σπ−, B− → ρ0π− and B̄ → ρ±π∓ decays in a valence quark triangle model, incorporating chiral symmetries. We find a good agreement with recent experimental data for D → σπ and for D → ρπ. We point out that a long-distance contribution due to the axial vector a1 meson pole, calculated by using chiral symmetry, can be relevant to explain D → ρπ and for lowering the ...

2014
Monica-Alexandrina Irimia

This paper contains an investigation of some aspects of Romanian modality constructed with auxiliaries. These forms can be combined either with the infinitive, or with overt (imperfective /perfective) aspectual morphology. In the latter case, they might give rise to interpretations which have been classified in Romanian grammars as presumptive (broadly described as referring to probability, unc...

Journal: :iranian journal of science and technology (sciences) 2007
a. jarrahpour

synthesis of some new monocyclic β-lactams containing a quaternary carbon center via a [2+2]cycloaddition reaction is described. the reaction of achiral diphenyl ketene with chiral aldimines derivedfrom chiral 2, 3, 4, 6-tetra-o-acetyl-β-d-galactopyranosylamine, 2, 3, 4, 6-tetra-o-acetyl-β-dglucopyranosylamine and different benzaldehydes resulted in the formation of β-lactams as singlediastereo...

2005
R. Noyori

Multinuclear organometallic species play a significant role in alkylation of carbonyl compounds. Enantioselective alkylation of aldehydes using a 1: 1 reagent/substrate stoichiometry is achievable by chirally modified lithium/magnesium binary organometallic reagents. For example, diethylmagnesium treated with di-O-lithio-(S)-2.2'dihydroxy1, 1'-binaphthyl reacts with benzaldehyde in a THFdimetho...

2006
Akinori Nishino Tetsuo Deguchi

The loop algebra L(sl2) symmetry is found in a sector of the nilpotent BazhanovStroganov model. The Drinfeld polynomial of a L(sl2)-degenerate eigenspace of the model is equivalent to the polynomial [4, 5, 10–14] which characterizes a subspace with the Isinglike spectrum of the superintegrable chiral Potts model.

Journal: :Journal of the American Chemical Society 2007
Vincent S Chan Robert G Bergman F Dean Toste

Chiral phosphines are essential ligands for asymmetric transitionmetal-catalyzed transformations.1 In 1972, Knowles and co-workers reported the first practical and highly asymmetric hydrogenation using P-stereogenic phosphines,2 yet planar chiral and point chiral phosphines are the most commonly employed ligands today. P-Stereogenic phosphines are less often utilized, in part due to the lack of...

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