UV/chlorine advanced oxidation process (AOP), as a potential alternative to UV/H2O2 in water treatment, may pose risk of increased disinfection by-product (DBP) formation and is great concern. In this paper, seven benzene derivatives, containing two chlorine-inert five chlorine-active compounds, were selected typical model DBP precursors, the effects medium pressure (MPUV/chlorine) on their chl...

he proposed Disinfectants/Disinfection By-products (D/DBP) Rule and the Enhanced Surface Water Treatment Rule (ESWTR) have prompted an industrywide evaluation of disinfection and treatment practices.1,2 One of the least expensive methods of limiting DBP formation is to use monochloramine instead of free chlorine to maintain a distribution system residual. Monochloramine limits free chlorine con...

BACKGROUND Epidemiologic clinical studies suggested that chronic exposure to chlorine products is associated with development of asthma and aggravation of asthmatic symptoms. However, its underlying mechanism was not clearly understood. Studies were undertaken to define the effects and mechanisms of chronic low-dose chlorine exposure in the pathogenesis of airway inflammation and airway hyperre...

In this study we demonstrate the feasibility of combined chlorine-35, sodium-23 and proton magnetic resonance imaging (MRI) at 9.4 Tesla, and present the first in vivo chlorine-35 images obtained by means of MRI. With the experimental setup used in this study all measurements could be done in one session without changing the setup or moving the subject. The multinuclear measurement requires a t...

Despite the low nutrient level and constant presence of secondary disinfectants, bacterial re-growth still occurs in drinking water distribution systems. The molecular mechanisms that starved bacteria use to survive low-level chlorine-based disinfectants are not well understood. The objective of this study is to investigate these molecular mechanisms at the protein level that prepare starved ce...

The chlorine radical is a potent atmospheric oxidant, capable of perturbing tropospheric oxidative cycles normally controlled by the hydroxyl radical. Significantly faster reaction rates allow chlorine radicals to expedite oxidation of hydrocarbons, including methane, and in polluted environments, to enhance ozone production. Here we present evidence, from the CARIBIC airborne dataset, for exte...

A gas diffusion sequential injection system for spectrophotometric determination of free chlorine is described. The detection is based in the colorimetric reaction between free chlorine and a low toxicity reagent o-dianisidine. A gas diffusion unit is used to isolate free chlorine from the sample in order to avoid possible interferences. This feature results from the conversion of free chlorine...

Reverse osmosis (RO) membranes have been widely used for desalination to purify water for drinking and other purposes. Although at present most RO membranes have no resistance to chlorine, chlorine-resistant membranes are being developed. Therefore, direct chlorine treatment or chlorine washing will be an option in preventing biofouling on chlorine-resistant membranes. Furthermore, if particle ...

Free chlorine and a combined organic N-chloramine (3-chloro-4,4-dimethyl-2-oxazolidinone, compound 1) were compared for efficacy as disinfectants against an admixture of cysts of Giardia lamblia and Giardia canis in water solution under a variety of test conditions; variables were pH, temperature, and water quality. In general, compound 1 was found to reduce the giardial excystation in the solu...

In a water distribution system (WDS), chlorine disinfection is important in preventing the spread of waterborne diseases. By strictly controlling residual chlorine throughout the WDS, water quality managers can ensure the satisfaction and safety of their customers. However, due to the travel time of water between the chlorine dosing point and any strategic monitoring points, water treatment pla...