The functionality or oxidation state of cobalt within a silica matrix can be tailored through the use of cationic surfactants and their halide counter ions during the sol-gel synthesis. Simply by adding surfactant we could significantly increase the amount of cobalt existing as Co3O4 within the silica from 44% to 77%, without varying the cobalt precursor concentration. However, once the surfact...

BACKGROUND Dyshidrotic eczema is a type of chronic intermittent dermatitis characterized by vesicles, dystrophic fingernail changes, and rarely bullae that affects the hands and feet. Many exogenous factors may trigger a flare including dermatophyte infections, contact irritants, and metal hypersensitivity. Although metal hypersensitivity does not play a role in all cases of dyshidrotic eczema,...

Three new volatile cobalt amidinate compounds were prepared: Co(tBuNC(R)NEt)2, R=Me, Et and n-Bu. They were characterized by elemental analysis, 1H NMR, X-ray structure analysis, melting point, vapor pressure, vaporization rate, thermal stability and chemical reactivity. They were found to evaporate cleanly without decomposition. Two of them are liquids at room temperature, allowing for more co...

The morphology and magnetic properties of diblock copolymer templated ferrimagnetic cobalt oxide nanoparticles are reported. Ring opening metathesis polymerization (ROMP) was used to synthesize a novel cobalt diblock copolymer, where cobalt is directly attached to the polymer chain. Gel permeation chromatography (GPC) was performed to determine molecular weight distribution. Transmission electr...

An investigation was carried out with the heavy metal Cobalt and legume plant soybean, in order to test the heavy metal accumulating ability of soybean. Cobalt was given to Soybean (Glycine max) plants in pot culture by soil drenching method. The accumulation and uptake of cobalt was tested from root, stem and leaves of treated plants. The results showed higher concentration (Co level (100-200 ...

A cobalamin (Cbl) cofactor in corrinoid iron-sulfur protein (CoFeSP) is the primary methyl group donor and acceptor in biological carbon oxide conversion along the reductive acetyl-CoA pathway. Changes of the axial coordination of the cobalt ion within the corrin macrocycle upon redox transitions in aqua-, methyl-, and cyano-Cbl bound to CoFeSP or in solution were studied using X-ray absorption...

Field experiment had been done Research and Production Station, National Research Centre, Nubaria location, to study the effect of cobalt on growth, seeds yield, oil yield and oil fatty acids constituents. The experiment containing 13 plots area were 15 m (5 X 3) containing 3 rows each, planted with 10 plants. The seedlings (at the third truly leaf) were irrigated with cobalt sulphate once with...

BACKGROUND Chronic renal hypoxia is suspected to play a pathogenic role in the genesis of diabetic nephropathy (DN). Cobalt enhances the activity of the hypoxia-inducible factor (HIF), a key factor in the defence against hypoxia. Its long-term effect on DN is evaluated. METHODS Cobalt chloride was given to hypertensive, type 2 diabetic rats with nephropathy (SHR/NDmcr-cp). Treatment was initi...

BACKGROUND In Korea, the prevalence of nickel allergy has shown a sharply increasing trend. Cobalt contact allergy is often associated with concomitant reactions to nickel, and is more common in Korea than in western countries. OBJECTIVE The aim of the present study was to investigate the prevalence of items that release nickel and cobalt on the Korean market. MATERIALS AND METHODS A total ...

Some of the component metals of the alloys used for total joint prostheses are toxic and dissolve in the body fluids. It is important to establish how toxic these metals are and to assess the risk of localised tissue necrosis around the prostheses. This has been investigated by incubating primary monolayer cultures of human synovial fibroblasts with various preparations of metals for periods up...