A chiral phosphine auxiliary was generated with excellent ee via catalytic asymmetric hydrophosphination of 3-(naphthalen-1-ylmethylene)pentane-2,4-dione. The subsequent metal complexation of the monophosphine yielded two different coordination complexes depending on the reaction conditions. The ortho-palladation of both coordination complexes resulted in the formation of a single dimeric phosp...

The effect of the solvent butanol on the complexation reaction of allylacetoacetate (AAA) with titanium tetraethoxide. (Ti(OEt)4) in molar ratio Ti(OEt)4:AAA = 1:1 was investigated by C-NMR, FT-IR spectroscopy and elemental analysis. The investigation shows that some ethoxy groups that are attached to the titanium are substituted with butoxy groups. The hydrolytic stability of the allylacetoace...

N-(9-Anthrylmethyl)amines which combine a fluorescent subunit and a chelate forming fragment have revealed a signal switching property in an aqueous solution upon complexation (off) with Cu(II) and liberation (on) of the probe molecule by substitution with an other ligand. The ligand exchange reaction between N-(phosphonomethyl)glycine (glyphosate), a typical herbicide, with N-(9-anthrylmethyl)...

Small molecules representing common synthetic polymers were subjected to photochemically induced hydrogen abstraction by benzophenone. Reactions were monitored using (1) H NMR to query the factors that influence preferential abstraction of protons in unique chemical environments. Differences in bond dissociation energies do not fully explain the observed hydrogen abstraction preferences. To tha...

A simultaneous injection effective mixing flow analysis (SIEMA) system was proposed for the spectrophotometric determination of palladium. The determination of palladium was based on its complexation reaction with 2-(5-bromo-2-pyridylazo)-5-[N-n-propyl-N-(3-sulfopropyl)amino]aniline (5-Br-PSAA) to form a blue complex, which has an absorption maximum at 612 nm. The analytical performances of the...

Copper(II) salts have long been used to kill algae in water systems, but they can precipitate as insoluble salts and form deposits on equipment surface. It is important to remove toxic metal from industrial waste because of contamination and toxicity issues. This paper discusses the testing and effects of various phosphonates to control copper-based fouling in the industrial water systems. It h...

[reaction: see text] Effects of metal cation recognition on photosensitized E-Z isomerization of 1,2-dichloroethylene have been investigated with two types of m,p- and o,o'-podand (oligo-oxyethylene unit) benzophenones 2 and 3. With increasing cation size, the %Z ratio at the photostationary state was changed from 67 to 91% for 2 but remained almost unchanged (86-88%) for 3. These results were ...

Novel bipyridylene-bridged bisporphyrin 1a, in which two porphyrin units were attached directly to symmetrical 4,4'-positions of the 2,2'-bipyridyl group, was synthesized by a nickel(0)-mediated homocoupling reaction of 5,10,15-tris(n-heptyl)-20-(2'-bromo-4'-pyridyl)porphyrinatozinc (3a) in 58% yield. Spatial geometries of two porphyrins in 1a were regulated by reversible complexation of the bi...

the dependence on ionic strength of protonation of glycine and its complexation with dioxouranium (vi) is reported in sodium perchlorate and sodium chloride solutions as background salts. the measurements have been performed at 25±0.1°c and various ionic strengths in the range 0.1 to 1.0 mol , using a combination of potentiometric and spectrophotometric techniques. the overall analysis  of the ...

Aim. To evaluate strength of magnesium ion complexes with levofloxacin and moxifloxacin. Materials methods . Complexation levofloxacin, moxifloxacin, reference ligands (ethylenediaminetetraacetate (EDTA), sodium citrate, glycine) ions in the range from 0.0 to 1.0 mmol / l was studied. The technique developed by authors (patent RU 2680519 C1) used measure rate a model formation reaction phosphat...