The Journal of Physical Chemistry C is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Article Correlating Acid Properties and Catalytic Function: A First-Principles Analysis of Alcohol Dehydration Pathways on Polyoxometalates Michael J. Janik, Josef Macht, Enrique Iglesia, and Matthew Neurock J. Phys. Chem. C, 2009, 113 (5), 1872-1885• DOI: 10.1021/...

We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2(nd) order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS β0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new g...

Herein we describe the preparation of hybrid polymer-inorganic interfaces by the immobilization of polyoxometalate nanoclusters on functionalized polymer surfaces. The polymeric surfaces were made of polystyrene-b-poly(acrylic acid)/polystyrene (PS-b-PAA/PS) blends by spin coating on a silicon wafer. The functionalization of the polymer film was obtained by interfacial migration of the amphiphi...

in this study, the effective factors on warpage in short fibre reinforced thermoplastic composites has been studied. first of all, the effective factors in manufacturing process were detected and then in order to decrease the number of experiments, the approach of design of experiments has been applied. by using micromechanics theory in composites and coefficients of thermal expansion models, a...

3. Soluble Metal Oxides 2459 3.1. Polyoxometalates 2459 3.2. Peroxotungstates 2459 3.3. Peroxomolybdates 2460 3.4. Methyltrioxorhenium 2461 3.5. Other Metal Oxides 2461 4. Metal Oxides Generated in Situ 2461 4.1. Selenium and Arsenic Compounds 2461 4.2. Simple Metal Salts 2462 5. Coordination Complexes 2463 5.1. Manganese Porphyrins 2463 5.2. Iron Porphyrins 2464 5.3. Manganese Salen Complexes ...

the creep behavior of basalt fiber reinforced epoxy (bfre) and glass fiber reinforced epoxy (gfre) composites was studied through tensile testing at high temperature. to study the effect of reinforcing epoxy, the micro glass powder (mgp) was added at various volume percentage into the epoxy resin in bfre composites. the initial strain for all the specimens were evaluated and compared with each ...

The synthesis of [K(4.5) ⊂ (ClSn(II))8P8W48O184](17.5-), featuring Sn(II) ions in trigonal-pyramidal SnO2Cl environment coordinating to the two inner rims of the wheel-shaped {P8W48}-type polyoxotungstate(vi) archetype, showcases how high chloride ligand concentrations as well as the control of the polyanion solubility via electrolytes and evaporation rates are essential to prevent numerous com...

The μ2-O atom in Anderson polyoxometalates was regioselectively activated by the introduction of protons, which, upon functionalization with triol ligands, could afford a series of unique χ isomers of the organically-derived Anderson cluster {[RCC(CH2O)3]MMo6O18(OH)3}(3-). Herein proton-controlled isomer transformation between the δ and χ isomer was observed by using the fingerprint region in t...