Hybrid-density functional theory (B3LYP/Def2-TZVPP) based method and NBOinterpretation were used to investigate the conformational behavior of 1,2-dihalodisilanes[halo=F (1), Cl (2), Br (3), I (4)]. The B3LYP/Def2-TZVPP results showed that the anticonformations of compounds 1-4 are more stable than their corresponding gaucheconformations. The stability of the anti conformation compared to the g...

Reaction of aryl methyl ketone with isatin in the presence of a base afforded 2- arylquinoline-4-carboxylic acid (3). Reaction of diazomethane with compound 3 yielded the ester 4. Compound 5 was prepared from the reaction of N, N'-dialkylethyl (or propyl) arnine with 4. Addition of hydrazine hydrate to compound 4a gave 2- (2- pyridyl) quinoline-4-carboxylic acid hydrazide (6). Reaction of l...

Introduction: Due to the emergence of resistance to antimalarial drugs as well as the lack of vaccination for malaria, there is an urgent demand for the development of new antimalarial alternatives. Recently, our research group developed a new set of 3-alkylpyridine marine alkaloid analogs, of which a compound known as compound 5 was found to be inactive against Plasmodium ...

the reaction of ch3o2 radicals with acetaldehyde on the solid surface of nh4no3 has been studied in a flow capillary reactor at low pressure and room temperature. the experiments were performed using epr spectrometer combined with the kinetic method of radicals freezing. peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...

on the basis of experimental data a kinetic model for the heterogeneous interaction between alkylperoxyradicals and organic compounds in langmuir- hinshelwood approach at room temperature has been offered.the effect of oxygen on the kinetics of process in the presence, [o2]o = 1 x 1011 – 1.6 x 1012 molecules.cm-2, and absence of oxygen has been analyzed. over time the chain degenerate branching...

background: thymus daenensis celak. is one of the medicinal plants which cultivated in iran. this plant involve high amount of polyphenols including thymol and carvacrol, which were reported to possess the high antioxidant activity. objective: antioxidative activity (aoa) and chemical constituents of thymus daenensis essential oil (tdeo) were examined. also, the effect of thermal treatments (80...

in this paper, we examine the effect of the energy difference between the l- and the -valleys in compound semiconductor materials, carrier effective mass, and the scattering processes on the electron transport characteristics in mesfets. to do this, we use the monte carlo simulation to demonstrate the superiority of the ingaas mesfet, made on a semi-insulating inp substrate, over both inp and ...

some plant extracts have been reported to exhibit antimicrobial properties. plant based pesticides appear to be an alternative for the synthetic pesticides because of their less dangerous impacts. the objective of this study was to assess the inhibitory activity of brassica napus water extract on mycelial growth of six phytopathogenic fungi rhizoctonia solani, phythophtora drechseleri, pythium ...