This work revisits capillary filling dynamics in the regime of nanometric to subnanometric channels. Using molecular dynamics simulations of water in carbon nanotubes, we show that for tube radii below one nanometer, both the filling velocity and the Jurin rise vary nonmonotonically with the tube radius. Strikingly, with fixed chemical surface properties, this leads to confinement-induced rever...

From the frontier of this paper, unless specified something else, let it be agreed that all groups into consideration are p-primary abelian for some arbitrary but fixed prime p written additively as is the custom when dealing with abelian group theory. The present short note is a contribution to a recent flurry of our results in [6]. Standardly, all notions and notations are essentially the sam...

For the past several years, there has been a lot of work in modelling complex simulations pertaining to motion of gases. In the work of [Fedkiw et al., 2001], a new approach to numerically simulate smoke was developed which incorporates the model proposed by Steinhoff and Underhill [Steinhoff and Underhill, 1994] known as “vorticity confinement”. Passive advection of smoke particles is consider...

We show that geometric confinement dramatically affects the shear-induced configurations of dense monodisperse colloidal suspensions; a new structure emerges, where layers of particles buckle to stack in a more efficient packing. The volume fraction in the shear zone is controlled by a balance between the viscous stresses and the osmotic pressure of a contacting reservoir of unsheared particles...

proton transfer (pt) and methyl group transfer (mgt) occurring in small biomimetic systems, formamide-formamidic acid (fa-fi), and n-formyl-n-methylformamide-(e)-methyl n-formylformimidate (nmfa-nmfi) are investigated in the gas phase and in single-walled carbon nanotubes by using the density functional theory and the oniom approach. it is shown that pt reaction is disfavoured in single-walled ...

The π-π interaction-dependent vapour pressure of phenanthrenequinone can be used to synthesize a phenanthrenequinone-confined ordered mesoporous carbon. Intimate contact between the insulating phenanthrenequinone and the conductive carbon framework improves the electrical conductivity. This enables a more complete redox reaction take place. The confinement of the phenanthrenequinone in the meso...

Closed field line confinement systems can develop convective cells when the MHD interchange stability criterion is violated. Using a previously derived set of reduced equations [ V.P. Pastukhov and N.V. Chudin, Plasma Physics Reports 27, 907 (2001)] it is shown that a true steady state solution can exist. For an assumed large-scale vortex pattern the plasma pressure profile that is implied by t...

The evolution of the vibrational spectra of the isoelectronic hydrogen clusters H26, H24He, and H24Li(+) is determined with pressure. We establish the vibrational modes with collective character common to the clusters, identify their individual vibrational fingerprints and discuss frequency shifts in the giga-Pascal pressure region. The results are of interest for the identification of doping e...

By means of atomistic empirical pseudopotentials combined with a configuration interaction approach, we have studied the optical properties of wurtzite ZnS quantum dots in the presence of strong quantum confinement effects as a function of pressure. We find the pressure coefficients of quantum dots to be highly size-dependent and reduced by as much as 23% in comparison to the bulk value of 63 m...

We have monitored ambulant intra-arterial blood pressure with the Oxford system in six subjects with autonomic failure who exhibited postural hypotension. Plotting pooled hourly mean values we have demonstrated a consistent circadian trend in blood pressure that was the inverse of the normal pattern, with the highest pressures at night and the lowest in the morning. In four subjects, confinemen...