This study investigates the activity of transition and alkaline-earth metal-doped catalysts supported on ceria or zirconia for the NOx-assisted oxidation of diesel particulate. A series of Cuand Fe-impregnated catalysts over CeO2 and ZrO2 supports were prepared by incipient wetness impregnation and characterized by BET, X-ray diffraction (XRD), and temperature-programmed reduction (TPR) experim...

Basic characteristics of heteropolyacids as green catalysts are overviewed, focusing on the various reaction fields in which the heteropolyacid catalysts function as acid and oxidation catalysts, and then two industrial processes which were made very green by the use of heteropolyacid catalysts in liquid biphase systems are described. In this context an interesting new reaction field formed at ...

The development of catalytic systems for the controlled oxidation of C−H bonds remains a highly sought-after goal in chemistry owing to the great utility of such transformation toward expediting the synthesis and functionalization of organic molecules. Cytochrome P450 monooxygenases are the catalysts of choice in the biological world for mediating the oxidation of sp and sp C−H bonds with a hig...

in the present work, highly efficient oxidation of sulfides catalyzed by moo2(acac)2 supported on multi-wall carbon nanotubes, mwcnts, modified with 1,2-diaminobenzene (dab) and 2-aminophenol (ap), at room temperature are reported. the effects of various parameters such as reaction time, solvent, catalyst amount, oxidant, etc, were studied. these heterogenized catalysts showed high activity in ...

in the present work, highly efficient oxidation of sulfides catalyzed by moo2(acac)2 supported on multi-wall carbon nanotubes, mwcnts, modified with 1,2-diaminobenzene (dab) and 2-aminophenol (ap), at room temperature are reported. the effects of various parameters such as reaction time, solvent, catalyst amount, oxidant, etc, were studied. these heterogenized catalysts showed high activity in ...

an efficient synthetic method for successful synthesis of amine denderon on sba-15 and related pd (ii) complex has been developed. this modified mesoporous material was characterized by various techniques such as tem, xrd, atomic absorption spectroscopy, n2 adsorption-desorption, and ft-ir. the catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of al...

Oxidation Catalysts In article number 2211260, Javier Pérez-Ramírez and co-workers report the design of a novel atomically dispersed Mn catalyst on CeO2 for selective oxidation ammonia to nitrous oxide. Effective stabilization low-valence isolated manganese sites results in formation unique catalytic ensemble, which enables facile oxygen activation leads unprecedented activity stability.

Oxidative degradation of Ethylendiamintetraacetic acid (EDTA) under UV irradiation can be carried out with oxygen absorbed from ambient air. This degradation process is a dual phase multi step process. In the first phase rapid cleavage of the substance is observed. At ambient temperature the intermediates slowly oxidize by forming carbon dioxide and water in a second phase, which is rate contro...

in this paper, labo3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. lacoo3 perovskite formulation showed the highest activity among labo3 (fe, mn and co) perovskite catalysts. so, lacoo3 perovskite based catalyst was s...

The development of efficient and stable water oxidation catalysts is necessary for the realization of practically viable water-splitting systems. Although extensive studies have focused on the metal-oxide catalysts, the effect of metal coordination on the catalytic ability remains still elusive. Here we select four cobalt-based phosphate catalysts with various cobalt- and phosphate-group coordi...