Among lithium battery cathode materials, Li1.2Ni0.13Mn0.54Co0.13O2 (LR-NMC) has a high theoretical capacity, but suffers from voltage and capacity fade during cycling. This is partially ascribed to transition metal cation migration, which involves the local transformation of honeycomb layered structure spinel-like nano-domains. Determination layered/spinel phase ratio powder X-ray diffraction d...

A femtosecond electron bunch is essential for the observation of ultrafast phenomena. In order to improve the time resolution of pulse radiolysis and ultrafast electron diffraction (UED), that involve the use of an ultrashort electron bunch and ultrashort light, a femtosecond photocathode RF gun was investigated experimentally. The bunch length due to space-charge and RF effects in the gun was ...

The time-temperature transformation behavior of a rapidly solidified (RS) Ti-24Al-11Nb alloy has been studied between 450 and 850 “C using X-ray diffraction, electron diffraction, transmission electron microscopy and microindentation methods. A revised isothermal transformation path from the initial B2 to the final cz? structure has been proposed: B2 (Pmjm)B19 (Pmma)-0’ (Cmcm) 0’ (Cmcm) a2 (P6,...

Recent progress in laser wakefield acceleration has led to the emergence of a new generation of electron and X-ray sources that may have enormous benefits for ultrafast science. These novel sources promise to become indispensable tools for the investigation of structural dynamics on the femtosecond time scale, with spatial resolution on the atomic scale. Here, we demonstrate the use of laser-wa...

Diffraction patterns of backscattered electrons can provide important crystallographic information with high spatial resolution. Recently, the dynamical theory of electron diffraction was applied to reproduce in great detail backscattering patterns observed in the scanning electron microscope (SEM). However, a fully quantitative comparison of theory and experiment requires angle-resolved measur...

Electron diffraction patterns of two-dimensional crystals of light-harvesting chlorophyll a/b-protein complex (LHC-II) from photosynthetic membranes of pea chloroplasts, tilted at different angles up to 60 degrees , were collected to 3.2 A resolution at -125 degrees C. The reflection intensities were merged into a three-dimensional data set. The Friedel R-factor and the merging R-factor were 21...

We present a method to treat spurious intensities in electron diffraction experiments. Coherent electron diffraction imaging requires proper data reduction before the application of phase retrieval algorithms. The presence of spurious intensities in the electron diffraction patterns makes the data reduction complicated and time consuming and jeopardizes the application of mathematical constrain...

-Thirty two boehmites, synthesized at temperatures ranging from room temperature to 300~ were examined by scanning electron microscopy, transmission electron microscopy, electron diffraction, X-ray powder diffraction, differential thermal analysis, and infrared spectroscopy. The results show that boehmite exhibits a continuous gradation in crystallite size ranging from single octahedral layers ...

Electron diffraction is a unique tool for analysing the crystal structures of very small crystals. In particular, precession electron diffraction has been shown to be a useful method for ab initio structure solution. In this work it is demonstrated that precession electron diffraction data can also be successfully used for structure refinement, if the dynamical theory of diffraction is used for...