This study aims to hydrophilize thermoplastic polyurethane (TPU) surface via selective segregation of amphiphilic block copolymers from bulk TPU matrix, namely “inverted grafting-to” approach. To this end, hydrophilic poly(ethylene glycol) (PEG) polymer chain was employed in either diblock (polycaprolactone-b-poly(ethylene (PCL-b-PEG)) or triblock (poly(ethylene glycol)-b-poly(propylene glycol)...

Ethylene glycol (EG) dan diethylene (DEG) adalah senyawa alkohol toksik berbentuk cairan dengan rasa manis; ini dapat ditemukan di beberapa alat rumah tangga, zat antibeku, pelarut automotif industri. Keracunan akibat konsumsi bisa fatal. EG DEG merupakan keadaan darurat medis yang membutuhkan diagnosis segera pengobatan agresif meliputi terapi suportif, antidot fomepizole atau ethanol, hemodia...

The objective was to test the hypothesis that the optimal cryoprotective agent for cryopreservation of human spermatozoa would be a solute for which cells have the highest plasma membrane permeability, resulting in the least amount of volume excursion during its addition and removal. To test this hypothesis, theoretical simulations were performed using membrane permeability coefficients to pred...

Ethylene glycol oligomers were visualized by indirect conductimetric detection based on dilution of the mobile phase due to the analytes. A high electrical conductivity background was maintained by the addition of 5 mM sodium nitrate in the mobile phase, and the analytes were visualized by decreases in the background when they eluted. A capacitively coupled contactless conductivity detector was...

We report data from infrared absorption (FTIR) and X-ray photoelectron spectroscopies that correlate the molecular conformation of oligo(ethylene glycol) (OEG)-terminated self-assembled alkanethiolate monolayers (SAMs) with the ability of these films to resist protein adsorption. We studied three different SAMs of alkanethiolates on both evaporated Au and Ag surfaces. The SAMs were formed from ...

A [2]rotaxane, in which the peptidic axle is protected from degradation by the macrocyclic sheath and terminated with a novel glycosidase-cleavable stopper, is rendered water-soluble by derivatisation with tetra(ethylene glycol) (TetEG) or glucosylated tetra(ethylene glycol) (Glc-TetEG) chains using the CuAAC 'click' reaction. The Glc-TetEG-derivatised rotaxane propeptide is >50 000 times more ...

After modification with monomethoxyl-poly(ethylene glycol)-5000, a recombinant intracellular uricase from Bacillus fastidiosus ATCC 29604 showed residual activity of about 65%, a thermo-inactivation half-life >85 h, a circulating half-life about 20 h in rats in vivo, consistent effects of common cations, and consistent optima for reaction temperature and pH. Thus, this uricase can be formulated...

The aqueous mixtures of light gas molecules under low-temperature and high-pressure conditions are candidates to form gas hydrate clathrates. The formation of gas hydrate may lead to various problems and extra charges in natural gas production and processing. The presence of hydrate crystals forming a stable solid phase can potentially block the wells, pipes, and process facilities. To avoid su...

The genetic toxicology of glycol ethers is reviewed. Ethylene glycol monomethyl ether (EGME) and diglyme have been more extensively studied than other members of this series. Most results indicate a lack of genotoxic potential, but certain tests have yielded positive responses with certain compounds. Ethylene glycol monoethyl ether (EGEE) induced sister chromatid exchanges and chromosomal aberr...

in the present work, graphene was synthesized by chemical vapor deposition (cvd) method. the structure of graphene was then confirmed by x-ray diffraction (xrd) and scanning electron microscope (tem) images. after that, mixed acid method (h2so4/hno3) was used to make the structure of synthesized graphenehydrophilic. in this method, carboxylate and hydroxide groups were linked to the edges of gr...