Electrolytic formic acid synthesis delivers green at the right concentration for emerging applications.

Retinal photoreceptors and retinal pigment epithelial (RPE) cells are among the cell types that are sensitive to poisoning with methanol and its toxic metabolite formic acid. When exposed to formic acid in vitro, cultured cell lines from photoreceptors (661W) and the RPE (ARPE-19) were previously shown to accumulate similar levels of formate, but cytotoxic effects are greater in 661W cells. Her...

The reported study was funded by RFBR under project No.20-33-90163. research at King Abdullah University of Science and Technology (KAUST) supported Saudi Aramco.

Metalloenzymes preorganize the reaction environment to steer substrate(s) along the required reaction coordinate. Here, we show that phosphine ligands selectively facilitate protonation of binuclear silver hydride cations, [LAg2(H)](+) by optimizing the geometry of the active site. This is a key step in the selective, catalysed extrusion of carbon dioxide from formic acid, HO2CH, with important...

The intramolecular tunneling of hydrogen atom in formic acid HCOOH at low temperatures is considered based on literature experimental data on C-O internal rotation. The energetic and geometric parameters as well as vibrational frequencies for formic acid in cis and trans configurations surrounded by 12 Ar atoms are calculated in the frame of the MP2 approach with extended basis sets. The temper...

An amphiphilic silk-like protein polymer was efficiently produced in the yeast Pichia pastoris. The secreted product was fully intact and was purified by solubilization in formic acid and subsequent precipitation of denatured host proteins upon dilution with water. In aqueous alkaline solution, the negatively charged acidic polymer assumed extended helical (silk III-like) and unordered conforma...

The efÞcacy of a formic acid pad formulation was Þeld tested for control of the honey bee parasitic miteVarroa destructorAnderson & Trueman in Florida and Texas. This pad formulation gave 39.8 11.1% control at the end of a 6-wk treatment period,which did not signiÞcantly differ from the initial sample date. Coumaphos treatment provided poor control (38.4 11.1%) over the 6-wk period, conÞrming r...

Hydrogen-dependent reduction of carbon dioxide to formic acid offers a promising route to greenhouse gas sequestration, carbon abatement technologies, hydrogen transport and storage, and the sustainable generation of renewable chemical feedstocks [1]. The most common approach to performing direct hydrogenation of CO2 to formate is to use chemical catalysts in homogeneous or heterogeneous reacti...