We recently reported the catalytic generation of hydrogen from water mediated through the in situ reduction of the molybdenum(IV)–oxo complex [(PY5Me2)MoO] 2+ (1; PY5Me2 1⁄4 2,6-bis(1,1-bis(2pyridyl)ethyl)pyridine) at a mercury electrode. To gain further insight into this unique molecular motif for hydrogen production, we have now examined the competence of this complex for the catalytic reduct...

Interactions between water and ferrous rocks are known to generate natural H 2 in oceanic continental domains via the oxidation of iron. Such generation has been mainly investigated through alteration Fe 2+ -silicate some -carbonates. So far, magnetite ( α -Fe 3 O 4 ) never considered as a potential source mineral for since it is by-product every chemical reaction leading formation , despite be...

For the first time, we demonstrate a photoelectrocatalysis technique for simultaneous surfactant pollutant degradation and green hydrogen generation using mesoporous WO3/BiVO4 photoanode under simulated sunlight irradiation. The materials properties such as morphology, crystallite structure, chemical environment, optical absorbance, bandgap energy of films are examined discussed. We have tested...