Selected metal-organic frameworks exhibiting representative properties--high surface area, structural flexibility, or the presence of open metal cation sites--were tested for utility in the separation of CO(2) from H(2) via pressure swing adsorption. Single-component CO(2) and H(2) adsorption isotherms were measured at 313 K and pressures up to 40 bar for Zn(4)O(BTB)(2) (MOF-177, BTB(3-) = 1,3,...

Porous aromatic frameworks (PAFs) incorporating a high concentration of acid functional groups possess characteristics that are promising for use in separating lanthanide and actinide metal ions, as required in the treatment of radioactive waste. These materials have been shown to be indefinitely stable to concentrated acids and bases, potentially allowing for multiple adsorption/stripping cycl...

−Singleand bi-solute sorption and desorption of 2-chlorophenol (2-CP) and 2,4,5-trichlorophenol (2,4,5TCP) in montmorillonite modified with hexadecyltrimethyl-ammonium (HDTMA) were investigated by sequential sorption and desorption. Effect of pH on the sequential sorption and desorption was investigated. As expected by the magnitude of octanol : water partition coefficient (K ow ), both sorptio...

Quite some bones of cows and pigs are discharged from home and restaurant industry as food wastes after cooking by boiling. This study conducted adsorption experiment of heavy metals using waste bones as an absorbent for recycling the waste bone and evaluated its feasibility. Sintered cattle bone (SCB) was manufactured in powder form after sintering at 550 ̊C 600 ̊C and pulverizing, and crystal s...

In this work, a systematic molecular simulation study was performed to compare the separation of CO2/N2 and CH4/N2 mixtures in two different classes of nanoporous materials, zeolites, and metal-organic frameworks (MOFs). For this purpose, three zeolites (MFI, LTA, and DDR) and seven MOFs (Cu-BTC, MIL-47 (V), IRMOF-1, IRMOF-12, IRMOF-14, IRMOF-11, and IRMOF-13) were chosen as the representatives...

High capacity, high selectivity, and low-cost regeneration conditions are the most important criteria by which new adsorbents for post-combustion carbon dioxide capture will be judged. The incorporation of N,N0-dimethylethylenediamine (mmen) into H3[(Cu4Cl)3(BTTri)8 (CuBTTri; H3BTTri 1⁄4 1,3,5-tri(1H1,2,3-triazol-4-yl)benzene), a water-stable, triazolate-bridged framework, is shown to drastical...

Four nanoporous carbons prepared by direct carbonization of non-permanent highly porous MOF [Zn3(BTC)2 · (H2O)3]n without any additional carbon precursors. The carbonization temperature plays an important role in the pore structures of the resultant carbons. The Brunauer-Emmett-Teller (BET) surface areas of four carbon materials vary from 464 to 1671 m(2) g(-1) for different carbonization tempe...

In this study, an experimental and analytical study on adsorption and adsorption kinetics of organic matters in titanium oxide (TiO2, Degussa P25) with synthetic wastewater was investigated. In order to understand the removal of different organic sizes in detail molecular weight (MW) distribution of organics matters was examined in terms of number and weight-average MW. The large MW (33950 dalt...

The large-scale isolation of specific isomers of amyl alcohols for applications in the chemical, pharmaceutical, and biochemical industries represents a challenging task due to the physicochemical similarities of these structural isomers. The homochiral metal-organic framework cadmium-BINOL (BINOL=1,1'-bi-2-naphthol) is suitable for the separation of pentanol isomers, combining adsorption selec...

Adsorption onto carbon nanotube bundles may find use in various applications such as gas pre-concentration and separation, and as a result it is of great interest to study the adsorption properties of such bundles. The adsorption of linear alkanes, with their systematic variation through chain length, is particularly useful to explore the effects of molecular length on adsorption characteristic...