Very low energy collision-induced dissociation of the deprotonated molecules of glycosyl esters of nucleoside pyrophosphates results in distinct fragmentation patterns that depend on the cis-trans configuration of the phosphodiester and 2″-hydroxyl groups of the glycosyl residue. In tandem mass spectrometry, sugar nucleotides with cis configuration produce only one, very abundant fragment that ...

According to data from stent-enhanced three-dimensional optical coherence tomography, incomplete stent apposition after side branch dilation in coronary bifurcation stenting can be reduced by the free carina type (no links bridged from a carina) and by distal cell rewiring. This is the first report to describe a bent stent technique that was devised to achieve the free carina type (no links bri...

The kinetics and mechanisms of the substitution reactions of trans-[Co(en)2CNCl]+ with unidentate anions,  , CN¯, I¯,  , Br¯ and SCN¯ in 60% v/v DMF-H2O binary solvent at 40.0±0.2 °C were studied spectrophotometrically. An Id mechanism was assigned for the replacement of chlorine by , CN¯ and I¯, an Ia one for...

The adsorption structures of dimethyl ether (DME) on silicalite-1 zeolite (MFI-type) are determined using single-crystal X-ray diffraction. The structure of low-loaded DME-silicalite-1 indicates that all DME molecules are located in the sinusoidal channel, which is the most stable sorption site based on the van der Waals interaction between DME and the framework. The configuration of guest mole...

We introduce a simple tool that can be used to reduce non-injective instances of the hidden shift problem over arbitrary group to injective instances over the same group. In particular, we show that the average-case non-injective hidden shift problem admit this reduction. We show similar results for (non-injective) hidden shift problem for bent functions. We generalize the notion of influence a...

Heritable differences in gene expression are caused by mutations in DNA sequences encoding cis-regulatory elements and trans-regulatory factors. These two classes of regulatory change differ in their relative contributions to expression differences in natural populations because of the combined effects of mutation and natural selection. Here, we investigate how new mutations create the regulato...

We consider the realization of affine ADE Lie algebras as string junctions on mutually non-local 7-branes in Type IIB string theory. The existence of the affine algebra is signaled by the presence of the imaginary root junction δ, which is realized as a string encircling the 7-brane configuration. The level k of an affine representation partially constrains the asymptotic (p, q) charges of stri...

trans-Caryophyllene is a major component in the essential oils of various species of medicinal plants used in popular medicine in Brazil. It belongs to the chemical class of the sesquiterpenes and has been the subject of a number of studies. Here, we evaluated the effects of this compound in airway smooth muscle. The biological activities of trans-caryophyllene were examined in isolated bath or...

Theoretical calculations for some structural and electronic properties of the azide moiety in the nucleoside reverse transcriptase (RT) inhibitor 3′-azido-3′deoxythymidine (AZT) are reported. These properties, which include geometrical properties in three dimensional space, Hirshfeld charges, electrostatic potential (MEP), vibrational frequencies, and core and valence ionization spectra, are em...