The title compound, C(16)H(20)Cl(2)O(8), contains a central bicyclo-[2.2.2]octane skeleton with slightly twisted conformation. In this structure, the C-C bond lengths are in the range 1.525 (2)-1.552 (2) Å. Two sides of this skeleton have cis,cis acet-oxy substituents and the Cl atoms have a trans arrangement. An extensive network of weak C-H⋯O interactions stabilizes the crystal structure.

Chiral cyclic compounds exhibited light-driven twisting by means of trans-cis photoisomerization in 1,4-dioxane solution, a neat film, and a liquid-crystalline host.

A photoresponsive single-handed double helical supramolecule composed of complementary strands bearing azobenzene moieties underwent a reversible trans-cis-isomerization regulated by photoirradiation, resulting in a change in its molecular length.

Fluorescence microscopy studies have shown that many proteins localize to highly specific subregions within bacterial cells. Analyzing the spatial distribution of low-abundance proteins within cells is highly challenging because information obtained from multiple cells needs to be combined to provide well-defined maps of protein locations. We present (to our knowledge) a novel tool for fast, au...

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The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.

| Introduction | Methods | Results | Discussion | Acknowledgments

A new diphosphine ligand assembled on the cyclotriphosphazene platform forms linear chelate and dimetallic bridged complexes with Au(I) and a cis-chelate complex with Pt(II).

In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl-Ni-Cl and cis-P-Ni-P planes. There is no significant inter-molecular inter-action except very weak C-H⋯Cl inter-actions. The crystal studied was a racemic ...