Deformation and breakup of a viscous drop in a Bingham liquid is investigated numerically with a volume-of-fluid scheme. Initially, a spherical drop is placed between two moving parallel plates. For our parameters, the matrix liquid has yielded. The competing effects driving the motion are the shear and interfacial tension. When interfacial tension effects dominate, the drop evolves to a steady...

We present a unified model for complete crystal-growth inhibition based on the thermodynamics of interfaces. The premise for our model is that the adsorption of inhibitor leads to a reduction in interfacial tension or edge energy for the crystal surface or step, respectively. In our formulation, the work to add a layer or grow a step increases due to the difference in interfacial tensions or ed...

The present paper reports a novel manipulation method for droplets using acoustic radiation pressure and acoustic streaming. In an acoustic field, droplets deform, oscillate and move in a wide range of applied frequencies. The behavior of a droplet depends on the droplet size, acoustic field and interfacial tension between the two phases. The acoustic field is controlled by the voltage and freq...

We have used dynamic interfacial tension measurements to understand the structure of the ordered monolayer at the hexadecane/water interface induced by the presence of surfactant molecules. No abrupt changes in the interfacial tension (gamma) are observed during the expansion and contraction cycle below the interfacial ordering temperature (Ti) as observed for alkanes in contact with air. The l...

The effect of molecular architecture of a surfactant, particularly the attachment position of benzene sulfonate on the hexadecane backbone, at the decane-water interface was investigated using atomistic MD simulations. We consider a series of surfactant isomers in the family of alkyl benzene sulfonates, denoted by m-C16, indicating a benzene sulfonate group attached to the mth carbon in a hexad...

The curvature-stress relation is studied for a film-substrate bilayer with the effect of interfacial slip and compared with that of an ideal interface without interfacial slip. The interfacial slip together with the dimensions, elastic and interfacial properties of the film and substrate layers can cause a significant deviation of curvature-stress relation from that with an ideal interface. The...

This work improved upon an effective micromechanical method to analyze the mechanical properties of three-dimensional particle-reinforced composites (PRC) with consideration of the interfacial debonding. By incorporating the interfacial debonding model, Mises yield criterion, and failure theory, the effects of particle shape, particle volume fraction, and loading condition on the mechanical pro...

An interfacial shear rheometer for stressand strain-controlled measurements at liquid interfaces is outlined. Experimental data are reported for the surfactant sorbitan tristearate on κ-carrageenan subphases. A setup combining interfacial rheometry with Brewster-angle Microscopy for realtime imaging of the interface is presented. INTRODUCTION Dynamic processes involving deformable fluid interfa...

To fully understand the polymer-filler interfacial interaction mechanism, we use a coarse-grained molecular dynamics simulation to mainly investigate the interfacial dynamic properties by tuning the polymer-filler interaction, temperature, chain length, volume fraction of filler, and size and shape of filler. The polymer beads around the filler exhibit an obvious layering behavior and a gradien...

The freezing of water is greatly influenced by the ice−water interfacial free energy. Yet, no consistent experimental measures of this thermodynamic parameter can be found. In this work we provide estimates for the ice Ih− water interfacial free energy at the normal melting temperature for different crystal planes (basal, primary prismatic, and secondary prismatic) using some widely used water ...