The electronic structures of monocationic tris[(5,10,15-pentafluorophenyl)-corrolato]iridium compounds, [Ir(tpfc)L2](+), where L = 4-cyanopyridine [1](+), pyridine [2](+), 4-methoxypyridine [3](+), or 4-(N,N'-dimethylamino)pyridine [4](+), have been probed by electron paramagnetic resonance (EPR) spectroscopy, Ir L3,2-edge X-ray absorption spectroscopy (XAS), UV/visible (UV-vis) spectroelectroc...

Group 9 transition metal complexes have been widely explored as therapeutic agents due to their unique geometry, their propensity to undergo ligand exchanges with biomolecules and their diverse steric and electronic properties. These metal complexes can offer distinct modes of action in living organisms compared to carbon-based molecules. In this study, we investigated the antimicrobial and ant...

A promising course for large-area ‘quasi’ single-crystal CVD diamond (scCVDD) is the heteroepitaxial growth on the multilayer structure Ir/YSZ/Si(001) [1] as developed at the University of Augsburg on 4inch wafers. Key issue is the similarity of the lattice constants of diamond (dDia = 3.567 Å) and Iridium (dIr = 3.834 Å). Figure 1 shows characterization results of two Diamond-on-Iridium (DoI) ...

Introduction: The use of long-half-life Cobalt source instead of iridium source will be very helpful in HDR brachytherapy for treatment of cervical cancer. The aim of this study was compared the treatment time with cobalt and iridium source in brachytherapy for treatment of cervical cancer using Tandem-ovoid applicator. Materials and Methods: In this study, 19...

A novel iridium complex, [bis-(2-phenylpyridine)(2-carboxy-4-dimethylaminopyridine)iridium(iii)] (N984), was synthesized and characterized using spectroscopic and electrochemical methods; a solution processable OLED device incorporating the N984 complex displays electroluminescence spectra with a narrow bandwidth of 70 nm at half of its intensity, with colour coordinates of x = 0.322; y = 0.529...

A novel iridium(III) complex-based chemosensor bearing the 5,6-bis(salicylideneimino)-1,10-phenanthroline ligand receptor was developed, which exhibited a highly sensitive and selective color change from colorless to yellow and a visible turn-off luminescence response upon the addition of Cu(II) ions. The interactions of this iridium(III) complex with Cu2+ ions and thirteen other cations have b...

Ir complexes of chiral phosphine-diamine ligands catalyse the hydrogenation and transfer hydrogenation of aryl-piperidin-4-yl methanones, and ketones bearing both an aryl group and secondary alkyl substituent with up to 98% e.e., and with substrate to catalyst ratios of up to 4000.

Synlett 2002, No. 12, Print: 02 12 2002. Art Id.1437-2096,E;2002,0,12,1954,1965,ftx,en;A30202ST.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0936-5214 Abstract: Two different synthetic reactions catalyzed by an iridium complex are discussed. The first is allylic alkylation and allylic amination. This reaction proceeds via a -allyl iridium intermediate. The selectivity strongly depends o...

We report the design and synthesis of a series of new cyclometalated iridium hydrides derived from the C-H bond activation of aromatic nitrones and the biological evaluation of these iridium hydrides as antitumor agents. The nitrone ligands are based on the structure of a popular antioxidant, α-phenyl-N-tert-butylnitrone (PBN). Compared to cisplatin, the iridium hydrides exhibit excellent antit...