Cold plasma and ozone sanitation of irrigation solutions can oxidize both microbes non-target micronutrients because their high oxidation-reduction potential (ORP) is a non-selective mode action. The objective this study was to evaluate the effects cold treatment on oxidation iron manganese in nutrient containing one four chelates (iron-ethylenediaminetetraacetic acid (Fe-EDTA), iron-diethylene...

Delivery of iron to K562 cells by diferric transferrin involves a cycle of binding to surface receptors, internalization into an acidic compartment, transfer of iron to ferritin, and release of apotransferrin from the cell. To evaluate potential feedback effects of iron on this system, we exposed cells to iron chelators and monitored the activity of the transferrin receptor. In the present stud...

Curcumin has been shown to have many potentially health beneficial properties in vitro and in animal models with clinical studies on the toxicity of curcumin reporting no major side effects. However, curcumin may chelate dietary trace elements and could thus potentially exert adverse effects. Here, we investigated the effects of a 6 month dietary supplementation with 0.2% curcumin on iron, zinc...

Total reduced sulfurs (TRS) include hydrogen sulfide (H2S), methyl mercaptan (methanethiol, CH3SH), dimethyl sulfide (CH3SCH3) and dimethyl disulfide (CH3S2CH3) and are referred to as noncondensible gases. They are part of a well-known environmental problem afflicting pulp mills exploiting the Kraft pulp mill process. These sulfur compounds are formed in the Kraft pulping process and come in co...

The synthesis, structure, and spectroscopic signatures of a series of four-coordinate iron(II) complexes of β-ketoiminates and their zinc(II) analogues are presented. An unusual five-coordinate iron(II) triflate with three oxygen bound protonated β-ketoimines is also synthesized and structurally characterized. Single-crystal X-ray crystallographic analysis reveals that the deprotonated bis(chel...

Red blood cells (RBCs) from patients with sickle cell anemia and thalassemia carry abnormal accumulations of molecular Fe(III) at the cytosol/membrane interface. The avidity of the red cell membrane for this iron has not been defined. Using open ghost membranes prepared from sickle RBC, we examined the ability of membrane-associated Fe(III) to resist removal by 15 chelators representing a 40-lo...

INTRODUCTION Uropathogenic Escherichia coli (UPEC), the causative agent of over 85% of urinary tract infections (UTIs), elaborate a number of siderophores to chelate iron from the host. On the other hand, the host immune imperative is to limit the availability of iron to the bacteria. Little is known regarding the mechanisms underlying this host-iron-UPEC interaction. Our objective was to deter...