In most bacteria the last step in synthesis of the pimelate moiety of biotin is cleavage of the ester bond of pimeloyl-acyl carrier protein (ACP) methyl ester. The paradigm cleavage enzyme is Escherichia coli BioH which together with the BioC methyltransferase allows synthesis of the pimelate moiety by a modified fatty acid biosynthetic pathway. Analyses of the extant bacterial genomes showed t...

an ever-increasing drift of energy consumption, unequal geographical distribution of natural wealth and the quest for low carbon fuel for a cleaner environment are sparking the production and use of biodiesels in many countries around the globe. in this work, jatropha and karanja biodiesels were produced from the respective crude vegetable oils through transesterification, and the different phy...

Protein methylation reactions can play important roles in cell physiology. After labeling intact Saccharomyces cerevisiae cells with S-adenosyl-l-[methyl-(3)H]methionine, we identified a major methylated 49-kDa polypeptide containing [(3)H]methyl groups in two distinct types of linkages. Peptide sequence analysis of the purified methylated protein revealed that it is eukaryotic elongation facto...

The purpose of this research is the synthesis alkyl esters from CPO through transesterification reaction using catalyst CaO-MgO. This experimental laboratory stages: (1) refinement, (2) determination free fatty acid numbers, (3) activation CaO-MgO catalysts, (5) with alcohol (methanol and ethanol), (6) identification components synthesized ester GC-MS,characterization including density, viscosi...

The Saccharomyces cerevisiae methyltransferase encoded by TMT1 catalyzes the AdoMet-dependent monomethylation of 3-isopropylmalate, an intermediate of the leucine biosynthetic pathway. The biological significance of methylating 3-isopropylmalate and the relationship between Tmt1 and the leucine biosynthetic pathway is not yet established. We present evidence here showing that methylation of 3-i...

In this study, corn oil as vegetable oil, chicken fat and fleshing oil as animal fats were used to produce methyl ester in a biodiesel pilot plant. The FFA level of the corn oil was below 1% while those of animal fats were too high to produce biodiesel via base catalyst. Therefore, it was needed to perform pretreatment reaction for the animal fats. For this aim, sulfuric acid was used as cataly...

The DPPH radical-scavenging abilities of the naturally occurring phenolic acid, 2,3,4-trihydroxybenzoic acid, and its methyl ester were evaluated. Both compounds in acetonitrile scavenged as many as four radicals compared to three or fewer radical consumption in acetone or ethanol. Only the ester showed relatively high ability in methanol. Oxidation with o-chloranil in acetonitrile resulted in ...

This is the first comprehensive study of the genetic analysis of the majority of oleoresin components of slash pine (Pinus elliottii). Pine oleoresin, the resin secreted from the pine tree, is a raw material widely used in industrial products. The objective of this study was to explore the genetic variation and correlation between the major oleoresin components of 50 open pollinated families of...

0016-2361/$ see front matter 2011 Elsevier Ltd. A doi:10.1016/j.fuel.2011.03.042 Abbreviations: CFME, chicken fat methyl esters; American society of testing and materials; KOH, p sodium hydroxide; KOMe, potassium methoxide; NaO ⇑ Corresponding author at: Department of Automo Kocaeli University, 41380 Kocaeli, Turkey Tel.: +90 3032203. E-mail addresses: [email protected], Canakci). In t...

The exact structure of the type-I11 isomer penta-, hexaand hepta-carboxylic porphyrinogens that are involved as intermediates in the conversion of uroporphyrinogen I11 into coproporphyrinogen 111 have been elucidated (Jackson et al., 1976). The corresponding porphyrins are to be found in the urine of patients suffering from the porphyrin-overproduction diseases symptomatic porphyria and congeni...