BACKGROUND Ship engine emissions are important with regard to lung and cardiovascular diseases especially in coastal regions worldwide. Known cellular responses to combustion particles include oxidative stress and inflammatory signalling. OBJECTIVES To provide a molecular link between the chemical and physical characteristics of ship emission particles and the cellular responses they elicit a...

Abstract—The major harmful automobile exhausts are nitric oxide (NO) and unburned hydrocarbon (HC). Reduction of NO using unburned fuel HC as a reductant is the technique used in hydrocarbon-selective catalytic reduction (HC-SCR). In this work, we study the microkinetic modelling of NO reduction using propene as a reductant on Pt catalysts. The selectivity of NO reduction to N2O is detected in ...

Vibrational spectroscopic investigations of hydrocarbon chain ordering in phosphatidylcholines (PCs) adsorbed from aqueous solution to a carbon tetrachloride-water interface presented here examine on a molecular level the organization pertinent to the surface characteristics displayed by these films. In a series of saturated symmetric and asymmetric chain PCs, both symmetric PCs with 16 or fewe...

The present XANES study aims at elucidating the roles of carbon deposits and metal sulfides in the catalyst deactivation in steam reforming reactions with the presence of sulfur. CeO(2)-Al(2)O(3)-supported Ni and Rh-based catalysts were tested in steam reforming of liquid hydrocarbon fuel containing 350 ppm sulfur for H(2) production at 800 degrees C. The Rh catalyst demonstrated much better su...

The present review addresses the latest findings and limitations in catalytic pyrolysis for processing of plastic waste into valuable fuels. Compared to thermal degradation plastics, provides better results regards quality obtained liquid hydrocarbon fuel. Different types catalysts can be used order improve plastics. Some most are different zeolites (HUSY, HZSM-5, Hβ), Fluid Catalytic Cracking ...

A computational uid dynamics and heat transfer analysis is performed to determine the convection and radiation heat transfer from an impinging ame jet to a plane surface. This paper focuses on analyzing the behavior of an impinging ame jet, including buoyancy e ects, turbulence in uence, and convective and radiative heat transfer processes. The combustion is modeled using a 12-species probabili...

There are many ways to reduce diesel engine exhaust emissions. However, NOx emission is difficult to reduce because the hydrocarbon (HC) concentration in a diesel engine is not sufficient for NOx conversion. Therefore, in order to create stoichiometric conditions in the De-NOx catalyst, a secondary injection system is designed to inject liquid HC into the exhaust pipe. The atomization and distr...

The analysis of conformational changes of hydrocarbon molecules is imperative in the prediction of their transport properties in different phases, such as evaporation/condensation coefficients (β) in the gas-liquid interface and evaporation rates of fuel droplets (k) in multiphases. In this letter, we analyze the effects of entropic contributions (T∆Sev(T)) to ∆Gev(T) during the evaporation/con...

The Fischer–Tropsch process is a collection of chemical reactions that converts mixture carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These occur in the presence metal catalysts, typically at temperatures 150–300°C (302–572°F) pressures one to several tens atmospheres. an important reaction both coal liquefaction gas liquids technology for producing In usual implement...

Abstract: In this study, the liquid-liquid equilibria of the mixtures consisted of ethanol, water, and the main components of gasoline fuel: pentane, hexane, and cyclohexane were experimentally determined. This study is related to the phase behavior when water in atmosphere is absorbed into ethanol + gasoline fuel (gasohol) and then possibly separates into two liquid phases in an automobile fue...