Salt metathesis reactions of Cp(2)(NR(2))ZrX (X = Cl, I, OTf) and lithium hydrosilazides ultimately afford hydride products Cp(2)(NR(2))ZrH that suggest unusual β-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp(2)Zr[N(SiHMe(2))t-Bu][N(SiHMe(2))(2)], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazi...

Silicon nanowires (SiNWs) are attracting growing interest due to their unique properties and promising applications in photovoltaic devices, thermoelectric devices, lithium-ion batteries, and biotechnology. Low-cost mass production of SiNWs is essential for SiNWs-based nanotechnology commercialization. However, economic, controlled large-scale production of SiNWs remains challenging and rarely ...

Platinum(II)-containing complexes with inherently chiral binaphthol derivatives display a versatile scaffold between random coils and single-turn helical strands, in which the conformational transition is controlled by the Pt···Pt and π-π interactions of alkynylplatinum(II) terpyridine moiety upon solvent and temperature modulation. The bisignate Cotton effect in the circular dichroism spectra ...

The formation, chemical reactivity, and spectral properties of a variety of new ,r-bonded and G-bonded organic derivatives of the transition metals are described. The Effective Atomic Number (E.A.N.) Rule predicts the existence of an isoelectronic series of mixed 'sandwich' complexes which contain a cyclo-pentadienyl ring and carbocyclic rings of varying sizes. Bis(it-cyclopenta-dienyl)iron or ...

Characterization and modeling of metal-semiconductor-metal (MSM) GaAs diodes using to evaporate SiO₂ and Pd simultaneously as a mixture electrode (called M-MSM diodes) compared with similar to evaporate Pd as the electrode (called Pd-MSM diodes) were reported. The barrier height (φ(b)) and the Richardson constant (A*) were carried out for the thermionic-emission process to describe well the cur...

The purpose of the study was to measure and compare the level of frictional resistance generated between conventional ceramic brackets (Transcend Series 6000, 3M Unitek, Monrovia, Calif), ceramic brackets with stainless steel slot (Clarity, 3M Unitek), conventional stainless steel brackets (Victory Series, 3M Unitek), and 3 different orthodontic wire alloys: stainless steel (stainless steel, SD...

Until recently, most microwave capacitors were based on fired multilayer ceramic technology. In this process, layers of highly conductive electrode metal alloys are interleaved with low-loss ceramic dielectrics in a multilayer fashion until the target capacitance is obtained. The resulting stack is then sintered into a monolithic structure in a high-temperature firing process. This process cont...