First-principles simulations have been performed for [001]-ordered Mn/Ge and Mn/GaAs " digital alloys " , focusing on the effects of i) a larger band-gap and ii) a different semiconducting host on the electronic structure of the magnetic semiconductors of interest. Our results for the exchange constants in Mn/Ge, evaluated using a frozen-magnon scheme, show that a larger band-gap tends to give ...

Copper indium gallium sulfide, CuIn1-xGaxS2 (CIGS2) solar cells prepared with chemical bath deposited heterojunction partner zinc-cadmium sulfide (ZnxCd1-xS) layer has exhibited better blue photon response and in turn, higher currents. This can be attributed to its higher bandgap than that of CdS. The open circuit voltages for CIGS2/ZnxCd1-xS were also higher than those of the CIGS2/CdS devices...

Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is responsible for epoxidation. This system leads to allcenes epoxidation such as styrene and cyclooctene. Epoxidation of cyclohexene produces cy...

Luminescent quantum dots (QDs) or rods are semiconductor nano-particles that may be used for a wide array of applications such as in electro-optical devices, spectral bar coding, tagging and light filtering. In the case under investigation, the nano-particles are cadmium-selenide (CdSe), though they can be made from cadmium-sulfide, cadmium-telluride or a number of other II-VI and III-V materia...

Recently, the synthesis of low-toxic quantum dots (QDs) and their application in biomedicine have attracted considerable attention. ZnSe nanocrystals doped with Mn ions which do not contain any Class A element (Cd, Pb, and Hg) can be used as a new generation of luminescent nanocrystals due to their strong dopant emission. In 2001, Norris et al. presented an organometallic synthetic route for th...

Using first principles calculations based on gradient corrected density functional theory we show that Mn atoms, which couple ferromagnetically in bulk Ga1-xMnxN, couple antiferromagnetically on its surface. This change in magnetic behavior is brought about by a contraction of the Mn-Mn and Mn-N bond lengths, which is significantly greater on the surface than in the bulk. The present study prov...

Abbreviations 2D, 3D 2-dimensional, 3-dimensional CZT cadmium zinc telluride EKG electric signal from the heart FBP filtered backprojection FOV field-of-view GE General Electric Ge(Li) germanium detector doped with lithium MLEM maximum likelihood expectation maximization NaI(Tl) sodium iodine doped with thallium NM nuclear medicine OSEM ordered subset expectation maximization PET positron emiss...

In sediments that contain iron monosulfide, cadmium, nickel, lead, zinc, and silver(I) form insoluble metal sulfides that lower the metal ion activity in the sediment-pore water system, thereby reducing toxicity. However, metal sulfides are susceptible to oxidation by molecular oxygen resulting in metal solubilization. To better understand the sources and sinks of metal sulfides in sediments, i...

In this paper we investigate the receipt of cadmium sulfide nanoparticles in the microemulsion system stabilized by nonionic surfactants, and the effect of the volume of microemulsion droplets and supersaturation on the size of the particles formed CdS. The photoluminescence spectrum microemulsion system containing nanoparticles of CdS, is shifted to shorter wavelengths of the spectrum and the ...

We report for the first time the enzymatic etching of cadmium sulfide nanoparticles (CdS NPs). The fluorescence of semiconductor CdS NPs is modulated irreversibly by an enzymatic reaction catalyzed by horseradish peroxidase (HRP). We observed blue-shifts of the corresponding fluorescence peaks for CdS NPs and a decrease in the intensity of the fluorescence signal.